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Effects of surface modification of beta-casio3 on electrospun poly(butylene succinate)/beta-casio3 composite fibers
Zhang, Daming1,2; Chang, Jiang1
刊名Materials chemistry and physics
2009-12-15
卷号118期号:2-3页码:379-384
关键词Composite materials Interfaces Microstructure Mechanical properties
ISSN号0254-0584
DOI10.1016/j.matchemphys.2009.08.005
通讯作者Chang, jiang(jchang@mail.sic.ac.cn)
英文摘要In this experiment, pure pbsu fibers, pbsu/12.5% beta-casio3, and pbsu/25% beta-casio3 composite fibers were fabricated by electrospinning. in order to investigate the effects of surface modification of beta-casio3 on composite fibers, beta-casio3 nanowires were surface esterified using dodecyl alcohol. sem micrographs showed that composite materials with modified beta-casio3 have homogeneous fibrous structures similar as that of pure pbsu fibers, while the fibers containing unmodified beta-casio3 were inhomogeneous and much larger in diameter, and also junctions where beta-casio3 agglomerated could be found. mechanical testing showed that with the addition of unmodified beta-casio3 into pbsu matrix, the tensile strength of fibrous materials decreased obviously, and the decrease degree increased with increased beta-casio3 content. however, the tensile stresses of composite materials after surface modification of beta-casio3 turned back and increased about 40% compared to those containing unmodified beta-casio3. all of these results suggested surface modification of beta-casio3 was an effective approach to obtain composite fibrous materials with better morphologies and enhanced mechanical properties, and this method is supposed to be feasible in other fibrous material systems. (c) 2009 elsevier b.v. all rights reserved.
WOS关键词L-LACTIC ACID ; INTERFACIAL INTERACTIONS ; GRAFTING POLYMERIZATION ; MECHANICAL-PROPERTIES ; HYDROXYAPATITE ; SCAFFOLD ; FABRICATION ; SILICA ; BONE ; ESTERIFICATION
WOS研究方向Materials Science
WOS类目Materials Science, Multidisciplinary
语种英语
出版者ELSEVIER SCIENCE SA
WOS记录号WOS:000271892800022
内容类型期刊论文
URI标识http://www.corc.org.cn/handle/1471x/2394364
专题中国科学院大学
通讯作者Chang, Jiang
作者单位1.Chinese Acad Sci, Shanghai Inst Ceram, Biomat & Tissue Engn Res Ctr, Shanghai 200050, Peoples R China
2.Chinese Acad Sci, Grad Sch, Shanghai 200050, Peoples R China
推荐引用方式
GB/T 7714
Zhang, Daming,Chang, Jiang. Effects of surface modification of beta-casio3 on electrospun poly(butylene succinate)/beta-casio3 composite fibers[J]. Materials chemistry and physics,2009,118(2-3):379-384.
APA Zhang, Daming,&Chang, Jiang.(2009).Effects of surface modification of beta-casio3 on electrospun poly(butylene succinate)/beta-casio3 composite fibers.Materials chemistry and physics,118(2-3),379-384.
MLA Zhang, Daming,et al."Effects of surface modification of beta-casio3 on electrospun poly(butylene succinate)/beta-casio3 composite fibers".Materials chemistry and physics 118.2-3(2009):379-384.
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