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Copolymers of thiophene and cyano-substituted phenylene: facile tuning of electronic energy levels and their photovoltaic application
Zou, Yingping1,2; Sang, Guangyi1,2; Zhou, Erjun1,2; Li, Yongfang1
刊名Macromolecular chemistry and physics
2008-02-20
卷号209期号:4页码:431-438
关键词Conjugated polymers Copolymerization Electronic energy levels Photophysical properties Photovoltaic properties
ISSN号1022-1352
DOI10.1002/macp.200700404
通讯作者Li, yongfang(liyf@iccas.ac.cn)
英文摘要A series of copolymers of thiophene and different molar ratios of docnp have been synthesized and characterized. the copolymers exhibit interesting tunable electronic energy levels and optoelectronic properties. the lumo energy levels of the copolymers decreased with increasing docnp content, while the homo levels changed only a little. the copolymer films show broad absorption and high absorption coefficients in the visible region, which could be beneficial to the application as photovoltaic materials in solar cells. the results show that the introduction of a proper amount of electron-acceptor groups in the polymer main chains induces an extension of the absorption spectra and improves the photovoltaic properties of the copolymers.
WOS关键词FIELD-EFFECT TRANSISTORS ; LIGHT-EMITTING-DIODES ; CONJUGATED POLYMER ; POLY(PHENYLENE VINYLENE)S ; ABSORPTION-SPECTRA ; SIDE-CHAINS ; ELECTROLUMINESCENT ; POLYTHIOPHENES ; CELLS ; UNITS
WOS研究方向Polymer Science
WOS类目Polymer Science
语种英语
出版者WILEY-V C H VERLAG GMBH
WOS记录号WOS:000253609200011
内容类型期刊论文
URI标识http://www.corc.org.cn/handle/1471x/2392783
专题中国科学院大学
通讯作者Li, Yongfang
作者单位1.Chinese Acad Sci, Key Lab Organ Solids, Beijing Natl Lab Mol Sci, Inst Chem, Beijing 100080, Peoples R China
2.Chinese Acad Sci, Grad Univ, Beijing 100039, Peoples R China
推荐引用方式
GB/T 7714
Zou, Yingping,Sang, Guangyi,Zhou, Erjun,et al. Copolymers of thiophene and cyano-substituted phenylene: facile tuning of electronic energy levels and their photovoltaic application[J]. Macromolecular chemistry and physics,2008,209(4):431-438.
APA Zou, Yingping,Sang, Guangyi,Zhou, Erjun,&Li, Yongfang.(2008).Copolymers of thiophene and cyano-substituted phenylene: facile tuning of electronic energy levels and their photovoltaic application.Macromolecular chemistry and physics,209(4),431-438.
MLA Zou, Yingping,et al."Copolymers of thiophene and cyano-substituted phenylene: facile tuning of electronic energy levels and their photovoltaic application".Macromolecular chemistry and physics 209.4(2008):431-438.
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