Enantioselective Rh-Catalyzed Hydrogenation of 3-Aryl-2-phosphonomethylpropenoates by a New Class of Chiral Ferrocenyl Diphosphine Ligands

	Enantioselective Rh-Catalyzed Hydrogenation of 3-Aryl-2-phosphonomethylpropenoates by a New Class of Chiral Ferrocenyl Diphosphine Ligands
	Wang, Dao-Yong 1,2; Hu, Xiang-Ping 1; Hou, Chuan-Jin 1; Deng, Jun 1,2; Yu, Sai-Bo 1,2; Duan, Zheng-Chao 1,2; Huang, Jia-Di 1,2; Zheng, Zhuo 1
刊名	organic letters
	2009-08-06
卷号	11 期号:15 页码:3226-3229
通讯作者	郑卓
产权排序	1;1
英文摘要	a new class of chiral ferrocenyl diphosphine ligands with an imidazole ring, (r(c), s(fc))-imiferrophos, has been prepared from acylferrocenes through a five-step transformation and successfully applied in the rh-catalyzed asymmetric hydrogenation of various 3-aryl-substituted 2-phosphonomethylpropenoates, in which a series of chiral 3-phosphono-2-arylmethylpropanoic acid derivatives were achieved in ee values of up to 98%.
WOS标题词	science & technology ; physical sciences
类目[WOS]	chemistry, organic
研究领域[WOS]	chemistry
关键词[WOS]	phosphine-phosphoramidite ligands ; phosphonic acid-derivatives ; glutamyl-gamma-glutamate ; asymmetric hydrogenation ; potent inhibitors ; metal-complexes ; stereoselective-synthesis ; selective inhibitors ; synthetase ; leads
收录类别	SCI ; IC ; CCR
原文出处	false
语种	英语
WOS记录号	WOS:000268479900017
公开日期	2010-11-30
内容类型	期刊论文
源URL	[http://159.226.238.44/handle/321008/102351]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
作者单位	1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China
推荐引用方式 GB/T 7714	Wang, Dao-Yong,Hu, Xiang-Ping,Hou, Chuan-Jin,et al. Enantioselective Rh-Catalyzed Hydrogenation of 3-Aryl-2-phosphonomethylpropenoates by a New Class of Chiral Ferrocenyl Diphosphine Ligands[J]. organic letters,2009,11(15):3226-3229.
APA	Wang, Dao-Yong.,Hu, Xiang-Ping.,Hou, Chuan-Jin.,Deng, Jun.,Yu, Sai-Bo.,...&Zheng, Zhuo.(2009).Enantioselective Rh-Catalyzed Hydrogenation of 3-Aryl-2-phosphonomethylpropenoates by a New Class of Chiral Ferrocenyl Diphosphine Ligands.organic letters,11(15),3226-3229.
MLA	Wang, Dao-Yong,et al."Enantioselective Rh-Catalyzed Hydrogenation of 3-Aryl-2-phosphonomethylpropenoates by a New Class of Chiral Ferrocenyl Diphosphine Ligands".organic letters 11.15(2009):3226-3229.