Synthesis of solid solution er2-xcexw3o12 and studies of their thermal expansion behavior | |
Wu, M. M.; Cheng, Y. Z.; Peng, J.; Xiao, X. L.; Chen, D. F.; Kiyanagi, R.; Fieramosca, J. S.; Short, S.; Jorgensen, J.; Hu, Z. B. | |
刊名 | Materials research bulletin
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2007-12-04 | |
卷号 | 42期号:12页码:2090-2098 |
关键词 | X-ray diffraction Thermogravimetric analysis Thermal expansion Crystal structure |
ISSN号 | 0025-5408 |
DOI | 10.1016/j.materresbull.2007.01.015 |
通讯作者 | Hu, z. b.(huzq@gucas.ac.cn) |
英文摘要 | The syntheses and structures of er2-xcexw3o12 were studied. it was found that pure phases could form only for 0.0 <= x <= 0.4 and 1.5 <= x <= 2.0. compounds with 0 <= x <= 0.4 have the hydrated orthorhombic structure at room temperature and transform to unhydrated orthorhombic one above 135 degrees c whereas samples with 1.5 <= x <= 2.0 crystallize in monoclinic structure. thermal expansion properties of er2-xcexw3o12 were studied with high temperature x-ray powder diffraction. samples with 0 <= x <= 0.4 exhibit negative thermal expansion in temperature range of 200-800 degrees c and higher cerium content leads to more negative thermal expansion coefficient. however, compounds with 1.5 <= x <= 2.0 show positive thermal expansion owing to the edge-sharing polyhedra. (c) 2007 elsevier ltd. all rights reserved. |
WOS关键词 | X-RAY-DIFFRACTION ; PHASE-TRANSITION ; TUNGSTATES ; Y2W3O12 ; ZRW2O8 ; MOLYBDATES |
WOS研究方向 | Materials Science |
WOS类目 | Materials Science, Multidisciplinary |
语种 | 英语 |
出版者 | PERGAMON-ELSEVIER SCIENCE LTD |
WOS记录号 | WOS:000251270000017 |
内容类型 | 期刊论文 |
URI标识 | http://www.corc.org.cn/handle/1471x/2383500 |
专题 | 中国科学院大学 |
通讯作者 | Hu, Z. B. |
作者单位 | 1.Grad Univ, Chinese Acad Sci, Coll Chem & Chem Engn, Beijing 100049, Peoples R China 2.China Inst Atom Energy, Beijing 102413, Peoples R China 3.Argonne Natl Lab, IPNS MSD, Argonne, IL 60439 USA |
推荐引用方式 GB/T 7714 | Wu, M. M.,Cheng, Y. Z.,Peng, J.,et al. Synthesis of solid solution er2-xcexw3o12 and studies of their thermal expansion behavior[J]. Materials research bulletin,2007,42(12):2090-2098. |
APA | Wu, M. M..,Cheng, Y. Z..,Peng, J..,Xiao, X. L..,Chen, D. F..,...&Hu, Z. B..(2007).Synthesis of solid solution er2-xcexw3o12 and studies of their thermal expansion behavior.Materials research bulletin,42(12),2090-2098. |
MLA | Wu, M. M.,et al."Synthesis of solid solution er2-xcexw3o12 and studies of their thermal expansion behavior".Materials research bulletin 42.12(2007):2090-2098. |
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