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Synthesis of solid solution er2-xcexw3o12 and studies of their thermal expansion behavior
Wu, M. M.; Cheng, Y. Z.; Peng, J.; Xiao, X. L.; Chen, D. F.; Kiyanagi, R.; Fieramosca, J. S.; Short, S.; Jorgensen, J.; Hu, Z. B.
刊名Materials research bulletin
2007-12-04
卷号42期号:12页码:2090-2098
关键词X-ray diffraction Thermogravimetric analysis Thermal expansion Crystal structure
ISSN号0025-5408
DOI10.1016/j.materresbull.2007.01.015
通讯作者Hu, z. b.(huzq@gucas.ac.cn)
英文摘要The syntheses and structures of er2-xcexw3o12 were studied. it was found that pure phases could form only for 0.0 <= x <= 0.4 and 1.5 <= x <= 2.0. compounds with 0 <= x <= 0.4 have the hydrated orthorhombic structure at room temperature and transform to unhydrated orthorhombic one above 135 degrees c whereas samples with 1.5 <= x <= 2.0 crystallize in monoclinic structure. thermal expansion properties of er2-xcexw3o12 were studied with high temperature x-ray powder diffraction. samples with 0 <= x <= 0.4 exhibit negative thermal expansion in temperature range of 200-800 degrees c and higher cerium content leads to more negative thermal expansion coefficient. however, compounds with 1.5 <= x <= 2.0 show positive thermal expansion owing to the edge-sharing polyhedra. (c) 2007 elsevier ltd. all rights reserved.
WOS关键词X-RAY-DIFFRACTION ; PHASE-TRANSITION ; TUNGSTATES ; Y2W3O12 ; ZRW2O8 ; MOLYBDATES
WOS研究方向Materials Science
WOS类目Materials Science, Multidisciplinary
语种英语
出版者PERGAMON-ELSEVIER SCIENCE LTD
WOS记录号WOS:000251270000017
内容类型期刊论文
URI标识http://www.corc.org.cn/handle/1471x/2383500
专题中国科学院大学
通讯作者Hu, Z. B.
作者单位1.Grad Univ, Chinese Acad Sci, Coll Chem & Chem Engn, Beijing 100049, Peoples R China
2.China Inst Atom Energy, Beijing 102413, Peoples R China
3.Argonne Natl Lab, IPNS MSD, Argonne, IL 60439 USA
推荐引用方式
GB/T 7714
Wu, M. M.,Cheng, Y. Z.,Peng, J.,et al. Synthesis of solid solution er2-xcexw3o12 and studies of their thermal expansion behavior[J]. Materials research bulletin,2007,42(12):2090-2098.
APA Wu, M. M..,Cheng, Y. Z..,Peng, J..,Xiao, X. L..,Chen, D. F..,...&Hu, Z. B..(2007).Synthesis of solid solution er2-xcexw3o12 and studies of their thermal expansion behavior.Materials research bulletin,42(12),2090-2098.
MLA Wu, M. M.,et al."Synthesis of solid solution er2-xcexw3o12 and studies of their thermal expansion behavior".Materials research bulletin 42.12(2007):2090-2098.
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