| Electrochemical characteristics of trioxane | |
| Tian Tian1,2; Liu Chang-Peng1; Liao Jian-Hui1; Xing Wei1; Lu Tian-Hong1 | |
| 刊名 | Chemical journal of chinese universities-chinese
 |
| 2007-12-10 | |
| 卷号 | 28期号:12页码:2390-2392 |
| 关键词 | Fuel cell Trioxane Electro-oxidation |
| ISSN号 | 0251-0790 |
| 通讯作者 | Xing wei(xingwei@ciac.jl.cn) |
| 英文摘要 | In the present communication, the electrooxidation of trioxane (1,3,5-trioxane)was studied as a new fuel for direct-oxidation-type fuel cells. direct-oxidation-type fuel cells have attracted much attention in recent years for the potential application as portable power sources; it can convert energy directly to electrical energy with high efficiency and low emission of pollution. trioxane is a solid and favors the logistics of safe transportation as a fuel. the electro-oxidation and electro-sorption characteristics of this fuel at platinum electrode were investigated with electrochemical methods. the cyclic voltammetric result suggests that the electrooxidation processes occur via chemisorption steps followed by surface reactions of adsorbed intermediates. the rate of electro-oxidation changed with the change of concentration of trioxane, acidity and temperature. the electro-oxidation of trioxane is carried out by an acid-catalyzed hydrolysis step in sulfuric acid solutions. |
| WOS关键词 | ETHANOL FUEL-CELL ; OXYGEN REDUCTION ; ELECTROOXIDATION ; OXIDATION ; METHANOL ; CATALYSTS ; ELECTROCATALYSTS ; SPECTROSCOPY ; PERFORMANCE ; CARBON |
| WOS研究方向 | Chemistry |
| WOS类目 | Chemistry, Multidisciplinary |
| 语种 | 英语 |
| 出版者 | HIGHER EDUCATION PRESS |
| WOS记录号 | WOS:000251953400036 |
| 内容类型 | 期刊论文 |
| URI标识 | http://www.corc.org.cn/handle/1471x/2383272 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Xing Wei |
| 作者单位 | 1.Chinese Acad Sci, Changchun Inst Appl Chem, Changchun 130022, Peoples R China 2.Grad Univ, Chinese Acad Sci, Beijing 100039, Peoples R China |
| 推荐引用方式 GB/T 7714 | Tian Tian,Liu Chang-Peng,Liao Jian-Hui,et al. Electrochemical characteristics of trioxane[J]. Chemical journal of chinese universities-chinese,2007,28(12):2390-2392. |
| APA | Tian Tian,Liu Chang-Peng,Liao Jian-Hui,Xing Wei,&Lu Tian-Hong.(2007).Electrochemical characteristics of trioxane.Chemical journal of chinese universities-chinese,28(12),2390-2392. |
| MLA | Tian Tian,et al."Electrochemical characteristics of trioxane".Chemical journal of chinese universities-chinese 28.12(2007):2390-2392. |
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