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	Na4h3[siw9al3(h2o)(3)o-37]center dot 12h(2)o/h2o: a new system for selective oxidation of alcohols with h2o2 as oxidant
	Wang, Jianmin; Yan, Liang; Qian, Guang; Li, Shunqing; Yang, Keli; Liu, Haitao; Wang, Xiaolai
刊名	Tetrahedron
	2007-02-10
卷号	63期号:8页码:1826-1832
ISSN号	0040-4020
DOI	10.1016/j.tet.2006.12.030
通讯作者	Wang, xiaolai(wangjianmin060102@yahoo.com.cn)
英文摘要	This work describes a catalytic system consisting of both na4h3[siw9al3(h2o)(3)o-37](.)12h(2)o(siw9al3) and water as solvents (a small quantity of organic solvents were used as co-solvent for a few substrates) that can be good for selective oxidation of alcohols to ketones (aldehydes) using 30% h2o2 without any phase-transfer catalyst under mild reaction conditions. the catalyst system allows easy product/catalyst separation. under the given conditions, the secondary hydroxyl group was highly chemoselectively oxidized to the corresponding ketones in good yields in the presence of primary hydroxyl group within the same molecule, and hydroxides are selectively oxidized even in the presence of alkene. benzylic alcohols were selectively oxidized to the corresponding benzaldehydes in good yields without over oxidation products in solvent-free conditions. nitrogen, oxygen, sulfur-based moieties, at least for the cases where these atoms are not susceptible to oxidation, do not interfere with the catalytic alcohol oxidation. (c) 2006 elsevier ltd. all rights reserved.
WOS关键词	AQUEOUS HYDROGEN-PEROXIDE ; MANGANESE-CONTAINING POLYOXOMETALATE ; PHASE-TRANSFER CONDITIONS ; ADIPIC ACID ; CATALYTIC EPOXIDATION ; SECONDARY ALCOHOLS ; ALKENE-OXIDATION ; OLEFINS ; CYCLOHEXENE ; MOLYBDENUM
WOS研究方向	Chemistry
WOS类目	Chemistry, Organic
语种	英语
出版者	PERGAMON-ELSEVIER SCIENCE LTD
WOS记录号	WOS:000244054900010
内容类型	期刊论文
URI标识	http://www.corc.org.cn/handle/1471x/2381125
专题	中国科学院大学
通讯作者	Wang, Xiaolai
作者单位	1.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab OxoSynth & Select Oxidat, Lanzhou 730000, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100000, Peoples R China
推荐引用方式 GB/T 7714	Wang, Jianmin,Yan, Liang,Qian, Guang,et al. Na4h3[siw9al3(h2o)(3)o-37]center dot 12h(2)o/h2o: a new system for selective oxidation of alcohols with h2o2 as oxidant[J]. Tetrahedron,2007,63(8):1826-1832.
APA	Wang, Jianmin.,Yan, Liang.,Qian, Guang.,Li, Shunqing.,Yang, Keli.,...&Wang, Xiaolai.(2007).Na4h3[siw9al3(h2o)(3)o-37]center dot 12h(2)o/h2o: a new system for selective oxidation of alcohols with h2o2 as oxidant.Tetrahedron,63(8),1826-1832.
MLA	Wang, Jianmin,et al."Na4h3[siw9al3(h2o)(3)o-37]center dot 12h(2)o/h2o: a new system for selective oxidation of alcohols with h2o2 as oxidant".Tetrahedron 63.8(2007):1826-1832.

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