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Non-isothermal crystallization kinetics and melting behaviors of poly(butylene succinate) and its copolyester modified with trimellitic imide units
Liu, Xiaoqing; Li, Chuncheng; Xiao, Yaonan; Zhang, Dong; Zeng, Wan
刊名Journal of applied polymer science
2006-11-05
卷号102期号:3页码:2493-2499
关键词Poly(butylene succinate) Trimellitic imide units Nonisothermal crystallization kinetics Melting behaviors
ISSN号0021-8995
DOI10.1002/app.24625
通讯作者Liu, xiaoqing(lizy@iccas.ac.cn)
英文摘要With the help of differential scanning calorimeter (dsc), the basic thermal behaviors, nonisothermal crystallization kinetics, and subsequent melting behaviors of poly(butylene succinate) (pbs) and its copolyester (pbstma) modified with trimellitic imide units were investigated in this paper. the dsc thermograms of pbs and pbstma showed that the crystallization behaviors of pbs were affected seriously because of the addition of a small quantity of trimellitic imide units. the nonisothermal crystallization processes of them were represented by the avrami equation modified by jeziorny and the method developed by ozawa. after that, the conception of "crystallization rate coefficient (crc)" introduced by khanna was employed. the values of crc for pbs and pbstma are 174.6 and 88.2 h(-1), respectively. at the end of this paper, the melting behaviors of pbs and pbstma after being cooled from 130 to 30 degrees c at different cooling rate were studied in detail. (c) 2006 wiley periodicals, inc.
WOS关键词MALEOPIMARIC ACID ANHYDRIDE ; POLY(TETRAMETHYLENE SUCCINATE) ; POLY(ETHYLENE SUCCINATE) ; ALIPHATIC POLYESTERS ; THERMAL-ANALYSIS ; BIODEGRADABILITY ; DEGRADATION ; MORPHOLOGY ; GLYCOL) ; DSC
WOS研究方向Polymer Science
WOS类目Polymer Science
语种英语
出版者JOHN WILEY & SONS INC
WOS记录号WOS:000240923900060
内容类型期刊论文
URI标识http://www.corc.org.cn/handle/1471x/2378754
专题中国科学院大学
通讯作者Liu, Xiaoqing
作者单位1.Chinese Acad Sci, Key Lab Engn Plast, Joint Lab Polymer Sci & Mat, Ctr Mol Sci,Inst Chem, Beijing 100080, Peoples R China
2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China
3.Xiangtan Univ, Dept Chem, Xiangtan, Peoples R China
推荐引用方式
GB/T 7714
Liu, Xiaoqing,Li, Chuncheng,Xiao, Yaonan,et al. Non-isothermal crystallization kinetics and melting behaviors of poly(butylene succinate) and its copolyester modified with trimellitic imide units[J]. Journal of applied polymer science,2006,102(3):2493-2499.
APA Liu, Xiaoqing,Li, Chuncheng,Xiao, Yaonan,Zhang, Dong,&Zeng, Wan.(2006).Non-isothermal crystallization kinetics and melting behaviors of poly(butylene succinate) and its copolyester modified with trimellitic imide units.Journal of applied polymer science,102(3),2493-2499.
MLA Liu, Xiaoqing,et al."Non-isothermal crystallization kinetics and melting behaviors of poly(butylene succinate) and its copolyester modified with trimellitic imide units".Journal of applied polymer science 102.3(2006):2493-2499.
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