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	Novel structure evolution of lanthanide-sip coordination polymers (nah2sip=5-sulfoisophthalic acid monosodium salt) from a 1d chain to a 3d network as a consequence of the lanthanide contraction effect
	Liu, QY; Xu, L
刊名	European journal of inorganic chemistry
	2005-09-05
期号	17页码:3458-3466
关键词	Crystal structures Hydrothermal synthesis Lanthanides Lanthanide contraction
ISSN号	1434-1948
DOI	10.1002/ejic.200500271
通讯作者	Xu, l()
英文摘要	The new series of lanthanide-sip coordination polymers [{ln(sip)(h2o)(5)}(h2o)(3)b](n) (ln = lu (1), yb (2), tm (3), and er (4)], [{ln(sip)(h2o)(4)}](n), (ln = ho (5), dy (6), tb (7), sm (8), pr (9), and nd (10)], and [{la(sip)(h2o)(3)}(h2o))](n) (11), have been synthesized by hydrothermal reactions of ln(2)o(3) and 5-sulfoisophthalic acid monosodium salt (nah2sip) at 160 degrees c and characterized by single-crystal x-ray diffraction. the unprecedented three structure types ongoing from lu-iii to l-iii have been established: type i for the small ions, lu, yb, tm, and er; type ii for the medium ions including ho, dy, tb, sm, pr, and nd; and type iii for the largest la ion. type i adopts a one-dimensional zigzag chain-like structure, type ii exhibits a two-dimensional undulate layer structure, and type iii features a two-dimensional double-layer pillared by sulfonate groups to form a three-dimensional open framework. the progressive structural changes from type i to type ii and to type iii with increasing atomic number were rationalized by the effect of the lanthanide contraction. their spectroscopic properties and thermal stability were also investigated. ((c) wiley-vch verlag gmbh & co. kgaa, 69451 weinheirn, germany, 2005).
WOS关键词	CRYSTAL-STRUCTURES ; PHOTOLUMINESCENT PROPERTIES ; COPPER-COMPLEXES ; LIGANDS ; CADMIUM(II) ; 4,4'-BIPYRIDINE ; FRAMEWORKS
WOS研究方向	Chemistry
WOS类目	Chemistry, Inorganic & Nuclear
语种	英语
出版者	WILEY-V C H VERLAG GMBH
WOS记录号	WOS:000231995500009
内容类型	期刊论文
URI标识	http://www.corc.org.cn/handle/1471x/2377628
专题	中国科学院大学
通讯作者	Xu, L
作者单位	1.Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fujian 350002, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China
推荐引用方式 GB/T 7714	Liu, QY,Xu, L. Novel structure evolution of lanthanide-sip coordination polymers (nah2sip=5-sulfoisophthalic acid monosodium salt) from a 1d chain to a 3d network as a consequence of the lanthanide contraction effect[J]. European journal of inorganic chemistry,2005(17):3458-3466.
APA	Liu, QY,&Xu, L.(2005).Novel structure evolution of lanthanide-sip coordination polymers (nah2sip=5-sulfoisophthalic acid monosodium salt) from a 1d chain to a 3d network as a consequence of the lanthanide contraction effect.European journal of inorganic chemistry(17),3458-3466.
MLA	Liu, QY,et al."Novel structure evolution of lanthanide-sip coordination polymers (nah2sip=5-sulfoisophthalic acid monosodium salt) from a 1d chain to a 3d network as a consequence of the lanthanide contraction effect".European journal of inorganic chemistry .17(2005):3458-3466.

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