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	Color tunable and near white-light emission of two solvent-induced 2d lead(ii) coordination networks based on a rigid ligand 1-tetrazole-4-imidazole-benzene
	Chen, Jun1,2; Zhang, Qing1,2; Liu, Zhi-Fa1; Wang, Shuai-Hua1; Xiao, Yu1,2; Li, Rong1,2; Xu, Jian-Gang1,2; Zhao, Ya-Ping1,2; Zheng, Fa-Kun1; Guo, Guo-Cong1
刊名	Dalton transactions
	2015
卷号	44期号:21页码:10089-10096
ISSN号	1477-9226
DOI	10.1039/c5dt00929d
通讯作者	Zheng, fa-kun(zfk@fjirsm.ac.cn)
英文摘要	Two new lead(ii) coordination polymers, [pb(no3)(tzib)](n) (1) and [pb(tzib) 2] n (2), were successfully synthesized from the reaction of a rigid ligand 1-tetrazole-4-imidazole-benzene (htzib) and lead(ii) nitrate in different solvents. the obtained polymers have been characterized by single-crystal x-ray diffraction analyses, which show that both polymers feature 2d layer structures. the inorganic anion nitrate in 1 shows a mu(2)-kappa o-3:kappa o-3 bridging mode to connect adjacent lead ions into a zigzag chain, and then the organic ligands tzib(-) join the neighboring chains into a 2d layer by a mu(3)-kappa n1:kappa n2:kappa n6 connection mode. in 2, there are two different bridging modes of the tzib(-) ligand: mu(3)-kappa n1:kappa n2:kappa n6 and mu 3-kappa n1:kappa n6 to coordinate the lead ions into a 2d layer structure. interestingly, both polymers displayed broadband emissions covering the entire visible spectra, which could be tunable to near white-light emission by varying excitation wavelengths.
WOS关键词	METAL-ORGANIC FRAMEWORK ; EMITTING-DIODES ; SOLID-STATE ; EXCITATION LIGHT ; LUMINESCENCE PROPERTIES ; LATTICE ARCHITECTURE ; HIGH-EFFICIENCY ; PHOTOLUMINESCENCE ; POLYMERS ; PHOSPHOR
WOS研究方向	Chemistry
WOS类目	Chemistry, Inorganic & Nuclear
语种	英语
出版者	ROYAL SOC CHEMISTRY
WOS记录号	WOS:000355000700040
内容类型	期刊论文
URI标识	http://www.corc.org.cn/handle/1471x/2376583
专题	中国科学院大学
通讯作者	Zheng, Fa-Kun
作者单位	1.Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100039, Peoples R China
推荐引用方式 GB/T 7714	Chen, Jun,Zhang, Qing,Liu, Zhi-Fa,et al. Color tunable and near white-light emission of two solvent-induced 2d lead(ii) coordination networks based on a rigid ligand 1-tetrazole-4-imidazole-benzene[J]. Dalton transactions,2015,44(21):10089-10096.
APA	Chen, Jun.,Zhang, Qing.,Liu, Zhi-Fa.,Wang, Shuai-Hua.,Xiao, Yu.,...&Guo, Guo-Cong.(2015).Color tunable and near white-light emission of two solvent-induced 2d lead(ii) coordination networks based on a rigid ligand 1-tetrazole-4-imidazole-benzene.Dalton transactions,44(21),10089-10096.
MLA	Chen, Jun,et al."Color tunable and near white-light emission of two solvent-induced 2d lead(ii) coordination networks based on a rigid ligand 1-tetrazole-4-imidazole-benzene".Dalton transactions 44.21(2015):10089-10096.

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