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	Porous azo-bridged porphyrin-phthalocyanine network with high iodine capture capability
	Li, Hui1,2; Ding, Xuesong1; Han, Bao-Hang1
刊名	Chemistry-a european journal
	2016-08-08
卷号	22期号:33页码:11863-11868
关键词	Gas adsorption Iodine Phthalocyanine Porous polymers Porphyrins
ISSN号	0947-6539
DOI	10.1002/chem.201602337
通讯作者	Ding, xuesong(dingxs@nanoctr.cn) ; Han, bao-hang(hanbh@nanoctr.cn)
英文摘要	We report a highly efficient iodine adsorbent achieved by rational design of a porous azo-bridged porphyrinphthalocyanine network (azoppn), which was synthesized by a catalyst-free coupling reaction between free-base 5,10,15,20-tetrakis(4-nitrophenyl)-porphyrin and nickel tetraaminophthlocyanine. azoppn has a permanent porous structure and plenty of porphyrin and phthalocyanine units in the skeleton as effective sorption sites. it displays excellent adsorption of iodine vapor up to 290 wt.% and also shows remarkable capability as adsorbent for iodine in solution. this strategy of combining physisorption with chemisorption in one adsorbent will pave the way for the development of new materials for iodine capture.
WOS关键词	CONJUGATED MICROPOROUS POLYMER ; COVALENT ORGANIC FRAMEWORK ; ELECTRICAL-CONDUCTIVITY ; HETEROGENEOUS CATALYSIS ; RADIOACTIVE IODINE ; VOLATILE IODINE ; GAS-STORAGE ; CO2 CAPTURE ; WASTE FORMS ; TEMPERATURE
WOS研究方向	Chemistry
WOS类目	Chemistry, Multidisciplinary
语种	英语
出版者	WILEY-V C H VERLAG GMBH
WOS记录号	WOS:000382921600049
内容类型	期刊论文
URI标识	http://www.corc.org.cn/handle/1471x/2376294
专题	中国科学院大学
通讯作者	Ding, Xuesong; Han, Bao-Hang
作者单位	1.Natl Ctr Nanosci & Technol, CAS Ctr Excellence Nanosci, CAS Key Lab Nanosyst & Hierarch Fabricat, Beijing 100190, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
推荐引用方式 GB/T 7714	Li, Hui,Ding, Xuesong,Han, Bao-Hang. Porous azo-bridged porphyrin-phthalocyanine network with high iodine capture capability[J]. Chemistry-a european journal,2016,22(33):11863-11868.
APA	Li, Hui,Ding, Xuesong,&Han, Bao-Hang.(2016).Porous azo-bridged porphyrin-phthalocyanine network with high iodine capture capability.Chemistry-a european journal,22(33),11863-11868.
MLA	Li, Hui,et al."Porous azo-bridged porphyrin-phthalocyanine network with high iodine capture capability".Chemistry-a european journal 22.33(2016):11863-11868.

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