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Prediction of ternary azeotropic refrigerants with a simple method
Zhao, Yanxing1,2; Gong, Maoqiong1; Dong, Xueqiang1; Zhang, Haiyang1,2; Guo, Hao1; Wu, Jianfeng1
刊名Fluid phase equilibria
2016-10-15
卷号425页码:72-83
关键词Ternary azeotropic Refrigerant Prediction Saddle point Maximum point
ISSN号0378-3812
DOI10.1016/j.fluid.2016.05.010
通讯作者Gong, maoqiong(gongmq@mail.ipc.ac.cn) ; Dong, xueqiang(dxq@mail.ipc.ac.cn)
英文摘要Refrigeration systems with azeotropic mixtures can achieve lower energy consumption, higher refrigeration capacity and coefficient of performance than both individual fluids and zeotropic refrigerants. in this paper, a simple method for predicting homogenous ternary azeotropic refrigerants was presented. the peng-robinson equation of state combined the van der waals mixing rule was proved successfully to represent the vapor + liquid equilibrium behavior of binary system and was employed to describe the ternary mixture phase equilibrium property. one hundred and seventy-one ternary systems were tested and eight azeotropes with six saddle-point azeotropes and two maximum-point azeotropes were found. the antoine equation was used to correlate the azeotropic pressures and the temperatures, which showed the similar behavior to pure fluids and revealed the reliability of the calculated value. it can be concluded that to form ternary azeotropes in refrigerant mixtures at least two subsystems are azeotropic and if all subsystems are azeotropic, the ternary system is more likely to form ternary azeotrope. (c) 2016 elsevier b.v. all rights reserved.
WOS关键词VAPOR-LIQUID-EQUILIBRIA ; ISOTHERMAL VLE MEASUREMENTS ; PLUS DIMETHYL ETHER ; 1,1,1-TRIFLUOROETHANE (HFC-143A)+1,1,1,2-TETRAFLUOROETHANE HFC-134A ; BINARY-MIXTURES ; ALTERNATIVE REFRIGERANT ; PHASE-EQUILIBRIA ; (1,1,2,2-TETRAFLUOROETHANE (R134) ; 1,1-DIFLUOROETHANE HFC-152A ; PENTAFLUOROETHANE HFC-125
WOS研究方向Thermodynamics ; Chemistry ; Engineering
WOS类目Thermodynamics ; Chemistry, Physical ; Engineering, Chemical
语种英语
出版者ELSEVIER SCIENCE BV
WOS记录号WOS:000382341700011
内容类型期刊论文
URI标识http://www.corc.org.cn/handle/1471x/2376253
专题中国科学院大学
通讯作者Gong, Maoqiong; Dong, Xueqiang
作者单位1.Chinese Acad Sci, Tech Inst Phys & Chem, Key Lab Cryogen, POB 2711, Beijing 100190, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100039, Peoples R China
推荐引用方式
GB/T 7714
Zhao, Yanxing,Gong, Maoqiong,Dong, Xueqiang,et al. Prediction of ternary azeotropic refrigerants with a simple method[J]. Fluid phase equilibria,2016,425:72-83.
APA Zhao, Yanxing,Gong, Maoqiong,Dong, Xueqiang,Zhang, Haiyang,Guo, Hao,&Wu, Jianfeng.(2016).Prediction of ternary azeotropic refrigerants with a simple method.Fluid phase equilibria,425,72-83.
MLA Zhao, Yanxing,et al."Prediction of ternary azeotropic refrigerants with a simple method".Fluid phase equilibria 425(2016):72-83.
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