A study on anode diffusion layer for performance enhancement of a direct methanol fuel cell | |
Liu, Guicheng1; Li, Xinyang2,5; Wang, Meng3; Wang, Manxiang4; Kim, Ji Young1; Woo, Jae Young1; Wang, Xindong3; Lee, Joong Kee1 | |
刊名 | Energy conversion and management |
2016-10-15 | |
卷号 | 126页码:697-703 |
关键词 | Direct methanol fuel cell Anode supporting layer Microporous layer Sintering treatment Surficial decoration |
ISSN号 | 0196-8904 |
DOI | 10.1016/j.enconman.2016.08.067 |
通讯作者 | Liu, guicheng(log67@163.com) ; Wang, xindong(echem@ustb.edu.cn) ; Lee, joong kee(leejk@kist.re.kr) |
英文摘要 | To optimize mass transfer property and electronic conductivity for direct methanol fuel cells with high discharge current density, in this paper, the influence of the modified components in anode diffusion layer on fuel cell performance has been investigated systematically. the modifications include binder type, carbon powder loading and sintering treatment in microporous layer, and surficial decoration of supporting layer. the fuel cell based on the hydrophilic diffusion layer which consisted of the microporous layer with nafion binder and the supporting layer modified by nafion emulsion, has shown the highest performance of 272.6 mw cm(-2) at 80 degrees c and 0.3 mpa oxygen. the results indicate that the nafion binder and sintering treatment are favorable for improving transfer properties of methanol solution and electron in anode microporous layer. the optimal carbon powder loading, 1.0 mg cm(-2), balances the conflict between mass transfer property and the contact area of the supporting and catalyst layers. the order mass transfer is also realized by the surficial decoration with 5 wt.% of nafion in supporting layer. in short, the hydrophilic anode diffusion layer is suitable for the fuel cell with high performance. (c) 2016 elsevier ltd. all rights reserved. |
WOS关键词 | MICROPOROUS LAYER ; CATALYST LAYER ; OPTIMIZATION ; DMFC ; MICROSTRUCTURE ; STABILITY ; CROSSOVER ; MEMBRANE ; CATHODE ; STACK |
WOS研究方向 | Thermodynamics ; Energy & Fuels ; Mechanics ; Physics |
WOS类目 | Thermodynamics ; Energy & Fuels ; Mechanics ; Physics, Nuclear |
语种 | 英语 |
出版者 | PERGAMON-ELSEVIER SCIENCE LTD |
WOS记录号 | WOS:000385326400061 |
内容类型 | 期刊论文 |
URI标识 | http://www.corc.org.cn/handle/1471x/2374821 |
专题 | 中国科学院大学 |
通讯作者 | Liu, Guicheng; Wang, Xindong; Lee, Joong Kee |
作者单位 | 1.Korea Inst Sci & Technol, Green City Res Inst, Ctr Energy Convergence Res, Hwarang Ro 14 Gil 5, Seoul 02792, South Korea 2.Beijing jiaotong Univ, Sch Civil Engn, Beijing 100044, Peoples R China 3.Univ Sci & Technol Beijing, Dept Phys Chem, 30 Xueyuan Rd, Beijing 100083, Peoples R China 4.Beijing Forestry Univ, Sch Environm Sci & Engn, Beijing 100083, Peoples R China 5.Univ Chinese Acad Sci, Coll Resources & Environm, Beijing 100049, Peoples R China |
推荐引用方式 GB/T 7714 | Liu, Guicheng,Li, Xinyang,Wang, Meng,et al. A study on anode diffusion layer for performance enhancement of a direct methanol fuel cell[J]. Energy conversion and management,2016,126:697-703. |
APA | Liu, Guicheng.,Li, Xinyang.,Wang, Meng.,Wang, Manxiang.,Kim, Ji Young.,...&Lee, Joong Kee.(2016).A study on anode diffusion layer for performance enhancement of a direct methanol fuel cell.Energy conversion and management,126,697-703. |
MLA | Liu, Guicheng,et al."A study on anode diffusion layer for performance enhancement of a direct methanol fuel cell".Energy conversion and management 126(2016):697-703. |
个性服务 |
查看访问统计 |
相关权益政策 |
暂无数据 |
收藏/分享 |
除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。
修改评论