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A study on anode diffusion layer for performance enhancement of a direct methanol fuel cell
Liu, Guicheng1; Li, Xinyang2,5; Wang, Meng3; Wang, Manxiang4; Kim, Ji Young1; Woo, Jae Young1; Wang, Xindong3; Lee, Joong Kee1
刊名Energy conversion and management
2016-10-15
卷号126页码:697-703
关键词Direct methanol fuel cell Anode supporting layer Microporous layer Sintering treatment Surficial decoration
ISSN号0196-8904
DOI10.1016/j.enconman.2016.08.067
通讯作者Liu, guicheng(log67@163.com) ; Wang, xindong(echem@ustb.edu.cn) ; Lee, joong kee(leejk@kist.re.kr)
英文摘要To optimize mass transfer property and electronic conductivity for direct methanol fuel cells with high discharge current density, in this paper, the influence of the modified components in anode diffusion layer on fuel cell performance has been investigated systematically. the modifications include binder type, carbon powder loading and sintering treatment in microporous layer, and surficial decoration of supporting layer. the fuel cell based on the hydrophilic diffusion layer which consisted of the microporous layer with nafion binder and the supporting layer modified by nafion emulsion, has shown the highest performance of 272.6 mw cm(-2) at 80 degrees c and 0.3 mpa oxygen. the results indicate that the nafion binder and sintering treatment are favorable for improving transfer properties of methanol solution and electron in anode microporous layer. the optimal carbon powder loading, 1.0 mg cm(-2), balances the conflict between mass transfer property and the contact area of the supporting and catalyst layers. the order mass transfer is also realized by the surficial decoration with 5 wt.% of nafion in supporting layer. in short, the hydrophilic anode diffusion layer is suitable for the fuel cell with high performance. (c) 2016 elsevier ltd. all rights reserved.
WOS关键词MICROPOROUS LAYER ; CATALYST LAYER ; OPTIMIZATION ; DMFC ; MICROSTRUCTURE ; STABILITY ; CROSSOVER ; MEMBRANE ; CATHODE ; STACK
WOS研究方向Thermodynamics ; Energy & Fuels ; Mechanics ; Physics
WOS类目Thermodynamics ; Energy & Fuels ; Mechanics ; Physics, Nuclear
语种英语
出版者PERGAMON-ELSEVIER SCIENCE LTD
WOS记录号WOS:000385326400061
内容类型期刊论文
URI标识http://www.corc.org.cn/handle/1471x/2374821
专题中国科学院大学
通讯作者Liu, Guicheng; Wang, Xindong; Lee, Joong Kee
作者单位1.Korea Inst Sci & Technol, Green City Res Inst, Ctr Energy Convergence Res, Hwarang Ro 14 Gil 5, Seoul 02792, South Korea
2.Beijing jiaotong Univ, Sch Civil Engn, Beijing 100044, Peoples R China
3.Univ Sci & Technol Beijing, Dept Phys Chem, 30 Xueyuan Rd, Beijing 100083, Peoples R China
4.Beijing Forestry Univ, Sch Environm Sci & Engn, Beijing 100083, Peoples R China
5.Univ Chinese Acad Sci, Coll Resources & Environm, Beijing 100049, Peoples R China
推荐引用方式
GB/T 7714
Liu, Guicheng,Li, Xinyang,Wang, Meng,et al. A study on anode diffusion layer for performance enhancement of a direct methanol fuel cell[J]. Energy conversion and management,2016,126:697-703.
APA Liu, Guicheng.,Li, Xinyang.,Wang, Meng.,Wang, Manxiang.,Kim, Ji Young.,...&Lee, Joong Kee.(2016).A study on anode diffusion layer for performance enhancement of a direct methanol fuel cell.Energy conversion and management,126,697-703.
MLA Liu, Guicheng,et al."A study on anode diffusion layer for performance enhancement of a direct methanol fuel cell".Energy conversion and management 126(2016):697-703.
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