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	A dual-walled cage mof as an efficient heterogeneous catalyst for the conversion of co2 under mild and co-catalyst free conditions
	Han, Yun-Hu1,2; Zhou, Zhong-Yuan1,3; Tian, Chong-Bin1; Du, Shao-Wu1
刊名	Green chemistry
	2016
卷号	18期号:14页码:4086-4091
ISSN号	1463-9262
DOI	10.1039/c6gc00413j
通讯作者	Du, shao-wu(swdu@fjirsm.ac.cn)
英文摘要	A novel 3d -> 3d interpenetrated zn-polyhedral mof [zn-6(tatab)(4)(dabco)(3)(h2o)(3)]center dot 12dmf center dot 9h(2)o (1) (h(3)tatab = 4,4',4 ''-s-triazine-1,3,5-triyl-tri-p-aminobenzoic acid, dabco = 1,4-diazabicyclo[2.2.2]-octane) based on a dual-walled icosahedral cage has been assembled by incorporating zinc paddlewheel units with nitrogen-rich tritopic carboxylate ligands. owing to the high density of lewis acid active sites and affinity to co2 of the cage, this material exhibits an excellent catalytic efficiency in the cycloaddition of propylene oxide with co2 into propylene carbonate under mild conditions (100 degrees c and ambient co2 pressure) with a high yield of 99% over 16 h. moreover, the catalytic reaction is environmentally friendly without any need for co-catalysts and solvents.
WOS关键词	METAL-ORGANIC FRAMEWORK ; CYCLIC CARBONATE SYNTHESIS ; FUNCTIONALIZED IRMOF-3 ; PROPYLENE CARBONATE ; GAS-ADSORPTION ; DIOXIDE ; EPOXIDES ; CYCLOADDITION ; CAPTURE ; OXIDE
WOS研究方向	Chemistry
WOS类目	Chemistry, Multidisciplinary
语种	英语
出版者	ROYAL SOC CHEMISTRY
WOS记录号	WOS:000379438200021
内容类型	期刊论文
URI标识	http://www.corc.org.cn/handle/1471x/2374681
专题	中国科学院大学
通讯作者	Du, Shao-Wu
作者单位	1.Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China 2.Chinese Acad Sci, Grad Univ, Beijing 100039, Peoples R China 3.Fuzhou Univ, Coll Chem, Fuzhou 350001, Peoples R China
推荐引用方式 GB/T 7714	Han, Yun-Hu,Zhou, Zhong-Yuan,Tian, Chong-Bin,et al. A dual-walled cage mof as an efficient heterogeneous catalyst for the conversion of co2 under mild and co-catalyst free conditions[J]. Green chemistry,2016,18(14):4086-4091.
APA	Han, Yun-Hu,Zhou, Zhong-Yuan,Tian, Chong-Bin,&Du, Shao-Wu.(2016).A dual-walled cage mof as an efficient heterogeneous catalyst for the conversion of co2 under mild and co-catalyst free conditions.Green chemistry,18(14),4086-4091.
MLA	Han, Yun-Hu,et al."A dual-walled cage mof as an efficient heterogeneous catalyst for the conversion of co2 under mild and co-catalyst free conditions".Green chemistry 18.14(2016):4086-4091.

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