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Photocatalytic hydrogen-evolution cross-couplings: benzene c -h amination and hydroxylation
Zheng, Yi-Wen1,2,3; Chen, Bin1,2; Ye, Pan1,2,3; Feng, Ke1,2; Wang, Wenguang3; Meng, Qing-Yuan1,2; Wu, Li-Zhu1,2; Tung, Chen-Ho1,2,3
刊名Journal of the american chemical society
2016-08-17
卷号138期号:32页码:10080-10083
ISSN号0002-7863
DOI10.1021/jacs.6b05498
通讯作者Wu, li-zhu(lzwu@mail.ipc.ac.cn) ; Tung, chen-ho(chtung@mail.ipc.ac.cn)
英文摘要We present a blueprint for aromatic c-h functionalization via a combination of photocatalysis and cobalt catalysis and describe the utility of this strategy for benzene amination and hydroxylation. without any sacrificial oxidant, we could use the dual catalyst systeth to produce aniline directly from benzene and ammonia, and phenol from benzene and water, both with evolution of hydrogen gas under unusually mild conditions in excellent yields and selectivities.
WOS关键词VISIBLE-LIGHT ; PHOTOREDOX CATALYSIS ; MERGING PHOTOREDOX ; PHENOL ; OXYGENATION ; BONDS ; CONVERSION ; OXIDANT ; AMINES
WOS研究方向Chemistry
WOS类目Chemistry, Multidisciplinary
语种英语
出版者AMER CHEMICAL SOC
WOS记录号WOS:000381715700004
内容类型期刊论文
URI标识http://www.corc.org.cn/handle/1471x/2374421
专题中国科学院大学
通讯作者Wu, Li-Zhu; Tung, Chen-Ho
作者单位1.Chinese Acad Sci, Tech Inst Phys & Chem, Key Lab Photochem Convers & Optoelect Mat, Beijing 100190, Peoples R China
2.Chinese Acad Sci, Univ Chinese Acad Sci, Beijing 100190, Peoples R China
3.Shandong Univ, Sch Chem & Chem Engn, Key Lab Colloid & Interface Chem, Minist Educ, Jinan 250100, Peoples R China
推荐引用方式
GB/T 7714
Zheng, Yi-Wen,Chen, Bin,Ye, Pan,et al. Photocatalytic hydrogen-evolution cross-couplings: benzene c -h amination and hydroxylation[J]. Journal of the american chemical society,2016,138(32):10080-10083.
APA Zheng, Yi-Wen.,Chen, Bin.,Ye, Pan.,Feng, Ke.,Wang, Wenguang.,...&Tung, Chen-Ho.(2016).Photocatalytic hydrogen-evolution cross-couplings: benzene c -h amination and hydroxylation.Journal of the american chemical society,138(32),10080-10083.
MLA Zheng, Yi-Wen,et al."Photocatalytic hydrogen-evolution cross-couplings: benzene c -h amination and hydroxylation".Journal of the american chemical society 138.32(2016):10080-10083.
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