Photocatalytic hydrogen-evolution cross-couplings: benzene c -h amination and hydroxylation | |
Zheng, Yi-Wen1,2,3; Chen, Bin1,2; Ye, Pan1,2,3; Feng, Ke1,2; Wang, Wenguang3; Meng, Qing-Yuan1,2; Wu, Li-Zhu1,2; Tung, Chen-Ho1,2,3 | |
刊名 | Journal of the american chemical society
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2016-08-17 | |
卷号 | 138期号:32页码:10080-10083 |
ISSN号 | 0002-7863 |
DOI | 10.1021/jacs.6b05498 |
通讯作者 | Wu, li-zhu(lzwu@mail.ipc.ac.cn) ; Tung, chen-ho(chtung@mail.ipc.ac.cn) |
英文摘要 | We present a blueprint for aromatic c-h functionalization via a combination of photocatalysis and cobalt catalysis and describe the utility of this strategy for benzene amination and hydroxylation. without any sacrificial oxidant, we could use the dual catalyst systeth to produce aniline directly from benzene and ammonia, and phenol from benzene and water, both with evolution of hydrogen gas under unusually mild conditions in excellent yields and selectivities. |
WOS关键词 | VISIBLE-LIGHT ; PHOTOREDOX CATALYSIS ; MERGING PHOTOREDOX ; PHENOL ; OXYGENATION ; BONDS ; CONVERSION ; OXIDANT ; AMINES |
WOS研究方向 | Chemistry |
WOS类目 | Chemistry, Multidisciplinary |
语种 | 英语 |
出版者 | AMER CHEMICAL SOC |
WOS记录号 | WOS:000381715700004 |
内容类型 | 期刊论文 |
URI标识 | http://www.corc.org.cn/handle/1471x/2374421 |
专题 | 中国科学院大学 |
通讯作者 | Wu, Li-Zhu; Tung, Chen-Ho |
作者单位 | 1.Chinese Acad Sci, Tech Inst Phys & Chem, Key Lab Photochem Convers & Optoelect Mat, Beijing 100190, Peoples R China 2.Chinese Acad Sci, Univ Chinese Acad Sci, Beijing 100190, Peoples R China 3.Shandong Univ, Sch Chem & Chem Engn, Key Lab Colloid & Interface Chem, Minist Educ, Jinan 250100, Peoples R China |
推荐引用方式 GB/T 7714 | Zheng, Yi-Wen,Chen, Bin,Ye, Pan,et al. Photocatalytic hydrogen-evolution cross-couplings: benzene c -h amination and hydroxylation[J]. Journal of the american chemical society,2016,138(32):10080-10083. |
APA | Zheng, Yi-Wen.,Chen, Bin.,Ye, Pan.,Feng, Ke.,Wang, Wenguang.,...&Tung, Chen-Ho.(2016).Photocatalytic hydrogen-evolution cross-couplings: benzene c -h amination and hydroxylation.Journal of the american chemical society,138(32),10080-10083. |
MLA | Zheng, Yi-Wen,et al."Photocatalytic hydrogen-evolution cross-couplings: benzene c -h amination and hydroxylation".Journal of the american chemical society 138.32(2016):10080-10083. |
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