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	Rh(iii)-catalyzed -fluoroalkenylation of n-nitrosoanilines with 2,2-difluorovinyl tosylates via c-h bond activation
	Tian, Miaomiao1; Yang, Xifa2; Zhang, Bo1; Liu, Bingxian1; Li, Xingwei1,2,3
刊名	Organic chemistry frontiers
	2018-12-07
卷号	5期号:23页码:3406-3409
ISSN号	2052-4129
DOI	10.1039/c8qo00947c
通讯作者	Li, xingwei(xwli@dicp.ac.cn)
英文摘要	Rh(iii)-catalyzed -fluoroalkenylation of n-nitrosoanilines with 2,2-difluorovinyl tosylates has been realized. this reaction proceeded via chelation-assisted c-h activation, olefin insertion and -f elimination, leading to the synthesis of monofluoroalkenes with high z-selectivity with respect to the olefin. this catalytic system is highly efficient over a broad range of substrates under mild and redox-neutral conditions.
WOS关键词	ALPHA-FLUOROALKENYLATION ; FLUORINE ; ARENES ; CATALYSIS ; NITROSO ; FUNCTIONALIZATIONS ; PHARMACEUTICALS ; INDOLES ; MIMICS
WOS研究方向	Chemistry
WOS类目	Chemistry, Organic
语种	英语
出版者	ROYAL SOC CHEMISTRY
WOS记录号	WOS:000450737800007
内容类型	期刊论文
URI标识	http://www.corc.org.cn/handle/1471x/2373031
专题	大连化学物理研究所
通讯作者	Li, Xingwei
作者单位	1.Henan Normal Univ, Sch Chem & Chem Engn, Henan Key Lab Organ Funct Mol & Drug Innovat, Xinxiang 453007, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China 3.Shaanxi Normal Univ, Sch Chem & Chem Engn, Xian 710119, Shaanxi, Peoples R China
推荐引用方式 GB/T 7714	Tian, Miaomiao,Yang, Xifa,Zhang, Bo,et al. Rh(iii)-catalyzed -fluoroalkenylation of n-nitrosoanilines with 2,2-difluorovinyl tosylates via c-h bond activation[J]. Organic chemistry frontiers,2018,5(23):3406-3409.
APA	Tian, Miaomiao,Yang, Xifa,Zhang, Bo,Liu, Bingxian,&Li, Xingwei.(2018).Rh(iii)-catalyzed -fluoroalkenylation of n-nitrosoanilines with 2,2-difluorovinyl tosylates via c-h bond activation.Organic chemistry frontiers,5(23),3406-3409.
MLA	Tian, Miaomiao,et al."Rh(iii)-catalyzed -fluoroalkenylation of n-nitrosoanilines with 2,2-difluorovinyl tosylates via c-h bond activation".Organic chemistry frontiers 5.23(2018):3406-3409.

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