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Ring-opening and cyclization of aziridines with aryl azides: metal-free synthesis of 6-(triflyloxy)quinolines
Yi, Ruxia1,2; Li, Xincheng1; Wan, Boshun1
刊名Organic chemistry frontiers
2018-12-07
卷号5期号:23页码:3488-3493
ISSN号2052-4129
DOI10.1039/c8qo00984h
通讯作者Wan, boshun(bswan@dicp.ac.cn)
英文摘要Ring-opening and cyclization of aziridines with aryl azides in the presence of tfoh has been developed. this strategy enables the construction of 6-(triflyloxy)quinoline cores by utilizing aziridine as a two-carbon surrogate. the introduction of a trifyl group at the 6-position of quinoline would allow further construction of carbon-carbon and carbon-heteroatom bonds in the cross-coupling reactions.
WOS关键词FORMAL 3+2+2 CYCLOADDITION ; POT 3-COMPONENT SYNTHESIS ; CROSS-COUPLING REACTIONS ; N-ACTIVATED AZIRIDINES ; C-H OXIDATION ; 2,3-DISUBSTITUTED QUINOLINES ; POVAROV REACTION ; ENANTIOSELECTIVE SYNTHESIS ; CATALYZED CYCLIZATION ; HIGHLY EFFICIENT
WOS研究方向Chemistry
WOS类目Chemistry, Organic
语种英语
出版者ROYAL SOC CHEMISTRY
WOS记录号WOS:000450737800020
内容类型期刊论文
URI标识http://www.corc.org.cn/handle/1471x/2373022
专题大连化学物理研究所
通讯作者Wan, Boshun
作者单位1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
推荐引用方式
GB/T 7714
Yi, Ruxia,Li, Xincheng,Wan, Boshun. Ring-opening and cyclization of aziridines with aryl azides: metal-free synthesis of 6-(triflyloxy)quinolines[J]. Organic chemistry frontiers,2018,5(23):3488-3493.
APA Yi, Ruxia,Li, Xincheng,&Wan, Boshun.(2018).Ring-opening and cyclization of aziridines with aryl azides: metal-free synthesis of 6-(triflyloxy)quinolines.Organic chemistry frontiers,5(23),3488-3493.
MLA Yi, Ruxia,et al."Ring-opening and cyclization of aziridines with aryl azides: metal-free synthesis of 6-(triflyloxy)quinolines".Organic chemistry frontiers 5.23(2018):3488-3493.
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