Ring-opening and cyclization of aziridines with aryl azides: metal-free synthesis of 6-(triflyloxy)quinolines | |
Yi, Ruxia1,2; Li, Xincheng1; Wan, Boshun1 | |
刊名 | Organic chemistry frontiers |
2018-12-07 | |
卷号 | 5期号:23页码:3488-3493 |
ISSN号 | 2052-4129 |
DOI | 10.1039/c8qo00984h |
通讯作者 | Wan, boshun(bswan@dicp.ac.cn) |
英文摘要 | Ring-opening and cyclization of aziridines with aryl azides in the presence of tfoh has been developed. this strategy enables the construction of 6-(triflyloxy)quinoline cores by utilizing aziridine as a two-carbon surrogate. the introduction of a trifyl group at the 6-position of quinoline would allow further construction of carbon-carbon and carbon-heteroatom bonds in the cross-coupling reactions. |
WOS关键词 | FORMAL 3+2+2 CYCLOADDITION ; POT 3-COMPONENT SYNTHESIS ; CROSS-COUPLING REACTIONS ; N-ACTIVATED AZIRIDINES ; C-H OXIDATION ; 2,3-DISUBSTITUTED QUINOLINES ; POVAROV REACTION ; ENANTIOSELECTIVE SYNTHESIS ; CATALYZED CYCLIZATION ; HIGHLY EFFICIENT |
WOS研究方向 | Chemistry |
WOS类目 | Chemistry, Organic |
语种 | 英语 |
出版者 | ROYAL SOC CHEMISTRY |
WOS记录号 | WOS:000450737800020 |
内容类型 | 期刊论文 |
URI标识 | http://www.corc.org.cn/handle/1471x/2373022 |
专题 | 大连化学物理研究所 |
通讯作者 | Wan, Boshun |
作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
推荐引用方式 GB/T 7714 | Yi, Ruxia,Li, Xincheng,Wan, Boshun. Ring-opening and cyclization of aziridines with aryl azides: metal-free synthesis of 6-(triflyloxy)quinolines[J]. Organic chemistry frontiers,2018,5(23):3488-3493. |
APA | Yi, Ruxia,Li, Xincheng,&Wan, Boshun.(2018).Ring-opening and cyclization of aziridines with aryl azides: metal-free synthesis of 6-(triflyloxy)quinolines.Organic chemistry frontiers,5(23),3488-3493. |
MLA | Yi, Ruxia,et al."Ring-opening and cyclization of aziridines with aryl azides: metal-free synthesis of 6-(triflyloxy)quinolines".Organic chemistry frontiers 5.23(2018):3488-3493. |
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