Alkenyl magnesium compounds: generation and synthetic application | |
Zhu, Miaomiao1,2; Liu, Liang1; Yu, Hai-Tao2; Zhang, Wen-Xiong1; Xi, Zhenfeng1 | |
刊名 | Chemistry-a european journal |
2018-12-20 | |
卷号 | 24期号:72页码:19122-19135 |
关键词 | Carbenoids Carbocycles Grignard reagents Magnesium Transmetalation |
ISSN号 | 0947-6539 |
DOI | 10.1002/chem.201802536 |
通讯作者 | Zhang, wen-xiong(wx_zhang@pku.edu.cn) ; Xi, zhenfeng(zfxi@pku.edu.cn) |
英文摘要 | Alkenyl magnesium compounds have received much attention in synthetic organic chemistry because of their high reactivity. this review summarizes three types of alkenyl magnesium compounds which contain at least one [mg-c=c] fragment, for example, (1) alkenyl grignard reagents prepared by halogen-magnesium exchange reaction; (2) alkenyl magnesium carbenoids prepared by halogen-magnesium exchange reaction or sulfoxide-magnesium exchange reaction; (3) magnesacarbocycles containing at least one alkenyl magnesium bond prepared from zr- or ti-catalyzed cyclomagnesation or transmetalation, as well as their further reactions and applications. |
WOS关键词 | FUNCTIONALIZED ALKENYLMAGNESIUM REAGENTS ; NITROGEN-CONTAINING HETEROCYCLES ; DEEP EUTECTIC SOLVENTS ; DIRECT N-ALKENYLATION ; HUMAN TOPOISOMERASE-I ; 1ST TOTAL-SYNTHESIS ; ALKYLIDENE CARBENOIDS ; GRIGNARD-REAGENTS ; STEREOSELECTIVE PREPARATION ; EXCHANGE-REACTION |
WOS研究方向 | Chemistry |
WOS类目 | Chemistry, Multidisciplinary |
语种 | 英语 |
出版者 | WILEY-V C H VERLAG GMBH |
WOS记录号 | WOS:000453829200003 |
内容类型 | 期刊论文 |
URI标识 | http://www.corc.org.cn/handle/1471x/2372964 |
专题 | 大连化学物理研究所 |
通讯作者 | Zhang, Wen-Xiong; Xi, Zhenfeng |
作者单位 | 1.Peking Univ, BNLMS, Key Lab Bioorgan Chem & Mol Engn, Minist Educ,Coll Chem, Beijing 100871, Peoples R China 2.Hebei Normal Univ, Coll Chem & Mat Sci, Shijiazhuang 050024, Hebei, Peoples R China |
推荐引用方式 GB/T 7714 | Zhu, Miaomiao,Liu, Liang,Yu, Hai-Tao,et al. Alkenyl magnesium compounds: generation and synthetic application[J]. Chemistry-a european journal,2018,24(72):19122-19135. |
APA | Zhu, Miaomiao,Liu, Liang,Yu, Hai-Tao,Zhang, Wen-Xiong,&Xi, Zhenfeng.(2018).Alkenyl magnesium compounds: generation and synthetic application.Chemistry-a european journal,24(72),19122-19135. |
MLA | Zhu, Miaomiao,et al."Alkenyl magnesium compounds: generation and synthetic application".Chemistry-a european journal 24.72(2018):19122-19135. |
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