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Palladium-catalyzed oxidative borylation of conjugated enynones through carbene migratory insertion: synthesis of furyl-substituted alkenylboronates
Ping, Yifan1; Chang, Taiwei1; Wang, Kang1; Huo, Jingfeng1; Wang, Jianbo1,2
刊名Chemical communications
2019-01-04
卷号55期号:1页码:59-62
ISSN号1359-7345
DOI10.1039/c8cc09024f
通讯作者Wang, jianbo(wangjb@pku.edu.cn)
英文摘要A palladium-catalyzed oxidative borylation reaction of conjugated enynones is developed. this reaction represents a new method for the synthesis of furyl-substituted alkenylboronates. the reaction works well with a series of conjugated enynones. boryl migratory insertion of the palladium carbene intermediate is proposed as the key step in these transformations.
WOS关键词ENE-YNE-KETONES ; C-C BOND ; CROSS-COUPLING REACTION ; METAL CARBENE ; REGIOSELECTIVE SYNTHESIS ; DIAZOCARBONYL COMPOUNDS ; N-TOSYLHYDRAZONES ; ORGANIC-SYNTHESIS ; TERMINAL ALKYNES ; ACTIVATION
WOS研究方向Chemistry
WOS类目Chemistry, Multidisciplinary
语种英语
出版者ROYAL SOC CHEMISTRY
WOS记录号WOS:000453549600006
内容类型期刊论文
URI标识http://www.corc.org.cn/handle/1471x/2372905
专题大连化学物理研究所
通讯作者Wang, Jianbo
作者单位1.Peking Univ, BNLMS, Key Lab Bioorgan Chem & Mol Engn, Minist Educ,Coll Chem, Beijing 100871, Peoples R China
2.Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China
推荐引用方式
GB/T 7714
Ping, Yifan,Chang, Taiwei,Wang, Kang,et al. Palladium-catalyzed oxidative borylation of conjugated enynones through carbene migratory insertion: synthesis of furyl-substituted alkenylboronates[J]. Chemical communications,2019,55(1):59-62.
APA Ping, Yifan,Chang, Taiwei,Wang, Kang,Huo, Jingfeng,&Wang, Jianbo.(2019).Palladium-catalyzed oxidative borylation of conjugated enynones through carbene migratory insertion: synthesis of furyl-substituted alkenylboronates.Chemical communications,55(1),59-62.
MLA Ping, Yifan,et al."Palladium-catalyzed oxidative borylation of conjugated enynones through carbene migratory insertion: synthesis of furyl-substituted alkenylboronates".Chemical communications 55.1(2019):59-62.
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