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	Preparation of novel aromatic-aliphatic poly(ketone ester)s through condensation of biomass-derived monomers
	Chen, Qin1,4; Ren, Tianhua1,4; Chai, Yang1,4; Guo, Yuanlong1,4; Ingram, Ian D. V.2,5; North, Michael2,5; Xie, Haibo1,4; Zhao, Zongbao Kent3,6
刊名	Chemcatchem
	2018-12-07
卷号	10期号:23页码:5377-5381
关键词	Vanillin Levulinic acid Lignocellulose Poly(ester ketone) Aldol condensation
ISSN号	1867-3880
DOI	10.1002/cctc.201801381
通讯作者	Xie, haibo(hbxie@gzu.edu.cn) ; Zhao, zongbao kent(zhaozb@dicp.ac.cn)
英文摘要	Novel unsaturated and saturated monomers with a hydroxyl group and a carboxylic group via aldol condensation reaction of lignin-derived aromatic aldehydes with levulinic acid were prepared through organocatalysis and hydrogenation, respectively. the catalytic process was optimized and the structure of the monomers were full characterized. the as-prepared monomers were ready for the subsequent condensation polymerization to achieve a serial of novel full biobased poly(ester ketone)s. the chemical-physical properties of the poly(ester ketone)s were evaluated. this provides a green upgrading strategy to prepare sustainable synthetic polymers from building blocks available on a large scale using a catalytic biorefinery approach.
WOS关键词	EFFICIENT SYNTHESIS ; AEROBIC OXIDATION ; GREEN CHEMISTRY ; LEVULINIC ACID ; LIGNIN ; CONVERSION ; VANILLIN ; TRANSFORMATION ; CHEMICALS ; PLATFORM
WOS研究方向	Chemistry
WOS类目	Chemistry, Physical
语种	英语
出版者	WILEY-V C H VERLAG GMBH
WOS记录号	WOS:000457345400004
内容类型	期刊论文
URI标识	http://www.corc.org.cn/handle/1471x/2372807
专题	大连化学物理研究所
通讯作者	Xie, Haibo; Zhao, Zongbao Kent
作者单位	1.Guizhou Univ, Dept Polymer Mat Engn Coll Mat Met, Guiyang 550025, Peoples R China 2.Univ York, Green Chem Ctr Excellence Dept Chem, York YO10 5DD, N Yorkshire, United Kingdom 3.Dalian Inst Chem Phys, Dalian 116023, Peoples R China 4.Guizhou Univ, Coll Mat & Met, Dept Polymer Mat & Engn, Guiyang 550025, Guizhou, Peoples R China 5.Univ York, Dept Chem, Green Chem Ctr Excellence, York YO10 5DD, N Yorkshire, England 6.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
推荐引用方式 GB/T 7714	Chen, Qin,Ren, Tianhua,Chai, Yang,et al. Preparation of novel aromatic-aliphatic poly(ketone ester)s through condensation of biomass-derived monomers[J]. Chemcatchem,2018,10(23):5377-5381.
APA	Chen, Qin.,Ren, Tianhua.,Chai, Yang.,Guo, Yuanlong.,Ingram, Ian D. V..,...&Zhao, Zongbao Kent.(2018).Preparation of novel aromatic-aliphatic poly(ketone ester)s through condensation of biomass-derived monomers.Chemcatchem,10(23),5377-5381.
MLA	Chen, Qin,et al."Preparation of novel aromatic-aliphatic poly(ketone ester)s through condensation of biomass-derived monomers".Chemcatchem 10.23(2018):5377-5381.

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