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Dynamical interference in the vibronic bond breaking reaction of hco
Han, Shanyu1,2; Zheng, Xianfeng3,4; Ndengue, Steve5; Song, Yu4; Dawes, Richard5; Xie, Daiqian1,6,7,8; Zhang, Jingsong4; Guo, Hua2
刊名Science advances
2019
卷号5期号:1页码:6
ISSN号2375-2548
DOI10.1126/sciadv.aau0582
通讯作者Dawes, richard(dawesr@mst.edu) ; Xie, daiqian(dqxie@nju.edu.cn) ; Zhang, jingsong(jingsong.zhang@ucr.edu) ; Guo, hua(hguo@unm.edu)
英文摘要First-principles treatments of quantum molecular reaction dynamics have reached the level of quantitative accuracy even in cases with strong non-born-oppenheimer effects. this achievement permits the interpretation of puzzling experimental phenomena related to dynamics governed by multiple coupled potential energy surfaces. we present a combined experimental and theoretical study of the photodissociation of formyl radical (hco). oscillations observed in the distribution of product states are found to arise from the interference of matter waves-a manifestation analogous to young's double-slit experiment.
WOS关键词STATE PHOTODISSOCIATION DYNAMICS ; POTENTIAL-ENERGY SURFACE ; 1ST ABSORPTION-BAND ; RENNER-TELLER ; AB-INITIO ; UNIMOLECULAR DISSOCIATION ; TRIATOMIC-MOLECULES ; DISTRIBUTIONS ; SPECTROSCOPY ; TRANSITION
WOS研究方向Science & Technology - Other Topics
WOS类目Multidisciplinary Sciences
语种英语
出版者AMER ASSOC ADVANCEMENT SCIENCE
WOS记录号WOS:000457547900003
内容类型期刊论文
URI标识http://www.corc.org.cn/handle/1471x/2372806
专题大连化学物理研究所
通讯作者Dawes, Richard; Xie, Daiqian; Zhang, Jingsong; Guo, Hua
作者单位1.Nanjing Univ, Sch Chem & Chem Engn, Key Lab Mesoscop Chem, Inst Theoret & Computat Chem, Nanjing 210093, Jiangsu, Peoples R China
2.Univ New Mexico, Dept Chem & Chem Biol, Albuquerque, NM 87131 USA
3.Anhui Normal Univ, Dept Phys, Anhui Prov Key Lab Optoelect Mat Sci & Technol, Wuhu 241000, Anhui, Peoples R China
4.Univ Calif Riverside, Dept Chem, Riverside, CA 92521 USA
5.Missouri Univ Sci & Technol, Dept Chem, Rolla, MO 65409 USA
6.Univ Sci & Technol China, Synerget Innovat Ctr Quantum Informat & Quantum P, Hefei 230026, Anhui, Peoples R China
7.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian 116023, Peoples R China
8.Chinese Acad Sci, Dalian Inst Chem Phys, Ctr Theoret Computat Chem, Dalian 116023, Peoples R China
推荐引用方式
GB/T 7714
Han, Shanyu,Zheng, Xianfeng,Ndengue, Steve,et al. Dynamical interference in the vibronic bond breaking reaction of hco[J]. Science advances,2019,5(1):6.
APA Han, Shanyu.,Zheng, Xianfeng.,Ndengue, Steve.,Song, Yu.,Dawes, Richard.,...&Guo, Hua.(2019).Dynamical interference in the vibronic bond breaking reaction of hco.Science advances,5(1),6.
MLA Han, Shanyu,et al."Dynamical interference in the vibronic bond breaking reaction of hco".Science advances 5.1(2019):6.
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