Electrochemical and thermodynamic investigation of diniconazole and triadimefon as corrosion inhibitors for copper in synthetic seawater
Hu, Lichao1; Zhang, Shengtao1; Li, Weihua2; Hou, Baorong2
刊名CORROSION SCIENCE
2010-09-01
卷号52期号:9页码:2891-2896
关键词Copper Eis Polarization Weight Loss Neutral Inhibition
ISSN号0010-938X
DOI10.1016/j.corsci.2010.04.038
文献子类Article
英文摘要This paper presents the investigation of diniconzole and triadimefon as chemical corrosion inhibitors for freshly polished copper in synthetic seawater (3.5% NaCl solution). Determination of weight loss, polarization curves, electrochemical impedance spectroscopy (EIS), and SEM, were performed to analyze the inhibiting performance of these compounds. Polarization curves show that they act as mixed-type inhibitors. EIS indicates that an adsorption film of the inhibitors is formed on copper surface. The highest values of inhibition efficiency are respectively, 99.2% and 97.3% at 100 mg/L concentration. Thermodynamic calculation suggests that chemisorptions between the compounds and copper are accordance with Langmuir adsorption isotherm. (C) 2010 Elsevier Ltd. All rights reserved.; This paper presents the investigation of diniconzole and triadimefon as chemical corrosion inhibitors for freshly polished copper in synthetic seawater (3.5% NaCl solution). Determination of weight loss, polarization curves, electrochemical impedance spectroscopy (EIS), and SEM, were performed to analyze the inhibiting performance of these compounds. Polarization curves show that they act as mixed-type inhibitors. EIS indicates that an adsorption film of the inhibitors is formed on copper surface. The highest values of inhibition efficiency are respectively, 99.2% and 97.3% at 100 mg/L concentration. Thermodynamic calculation suggests that chemisorptions between the compounds and copper are accordance with Langmuir adsorption isotherm. (C) 2010 Elsevier Ltd. All rights reserved.
学科主题Materials Science, Multidisciplinary ; Metallurgy & Metallurgical Engineering
URL标识查看原文
语种英语
WOS记录号WOS:000280272200017
公开日期2010-12-24
内容类型期刊论文
源URL[http://ir.qdio.ac.cn/handle/337002/5185]  
专题海洋研究所_海洋腐蚀与防护研究发展中心
作者单位1.Chongqing Univ, Coll Chem & Chem Engn, Chongqing 400044, Peoples R China
2.Chinese Acad Sci, Inst Oceanol, Key Lab Corros Sci, Qingdao 266071, Peoples R China
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GB/T 7714
Hu, Lichao,Zhang, Shengtao,Li, Weihua,et al. Electrochemical and thermodynamic investigation of diniconazole and triadimefon as corrosion inhibitors for copper in synthetic seawater[J]. CORROSION SCIENCE,2010,52(9):2891-2896.
APA Hu, Lichao,Zhang, Shengtao,Li, Weihua,&Hou, Baorong.(2010).Electrochemical and thermodynamic investigation of diniconazole and triadimefon as corrosion inhibitors for copper in synthetic seawater.CORROSION SCIENCE,52(9),2891-2896.
MLA Hu, Lichao,et al."Electrochemical and thermodynamic investigation of diniconazole and triadimefon as corrosion inhibitors for copper in synthetic seawater".CORROSION SCIENCE 52.9(2010):2891-2896.
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