Studies on two coordination polymers [M(mu(4)-pz25dc)](n) (M = Cd or Zn, pz25dc=pyrazine-2,5-dicarboxylato) with three-dimensional pillared-layer three-nodal framework: Synthesis, structural characterization, strong optical non-linearities and optical limiting properties

doi:10.1016/j.jorganchem.2009.07.005

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	Studies on two coordination polymers [M(mu(4)-pz25dc)](n) (M = Cd or Zn, pz25dc=pyrazine-2,5-dicarboxylato) with three-dimensional pillared-layer three-nodal framework: Synthesis, structural characterization, strong optical non-linearities and optical limiting properties
	Liu, Fa-Qian 1; Li, Rong-Xun 1; Deng, Yue-Yi 1; Li, Wei-Hua 2; Ding, Nai-Xiu 1; Liu, Guang-Ye 1
刊名	JOURNAL OF ORGANOMETALLIC CHEMISTRY
	2009-10-15
卷号	694 期号:22 页码:3653-3659
关键词	Coordination Polymers Third-order Nlo Properties Optical Limiting Pyrazine-2 5-dicarboxylato
ISSN号	0022-328X
DOI	10.1016/j.jorganchem.2009.07.005
文献子类	Article
英文摘要	Two isomorphous new candidates [M(mu(4)-pz25dc)](n) (M = Cd, 1; Zn, 2; pz25dc = pyrazine-2,5-dicarboxylato)for nonlinear optical (NLO) materials have been synthesized hydrothermally and characterized crystallographically as pillared-layer three-nodal frameworks with one four-connected metal nodes and two crystallographically different four-connected ligand nodes. Their optical non-linearities are measured by the Z-Scan technique with an 8 ns pulsed laser at 532 nm. These two coordination polymers both exhibit strong NLO absorptive abilities [alpha(2) = (63 +/- 6) x 10 (12) mW (1) 1, ( 46 +/- 6) x 10 (11) mW (1) 2] and effective self-focusing performance [n(2) = (67 +/- 5) x 10 (18) 1, (13 +/- 3) x 10 (18) m(2) W (1) 2] in 1.02 x 10 (4) 1 and 1.05 x 10 (4) mol dm (3) 2 DMF solution separately. The values of the limiting threshold are also measured from the optical limiting experimental data. The heavy atom effect plays important role in the enhancement of optical non-linearities and optical limiting properties. (C) 2009 Elsevier B. V. All rights reserved.; Two isomorphous new candidates [M(mu(4)-pz25dc)](n) (M = Cd, 1; Zn, 2; pz25dc = pyrazine-2,5-dicarboxylato)for nonlinear optical (NLO) materials have been synthesized hydrothermally and characterized crystallographically as pillared-layer three-nodal frameworks with one four-connected metal nodes and two crystallographically different four-connected ligand nodes. Their optical non-linearities are measured by the Z-Scan technique with an 8 ns pulsed laser at 532 nm. These two coordination polymers both exhibit strong NLO absorptive abilities [alpha(2) = (63 +/- 6) x 10 (12) mW (1) 1, ( 46 +/- 6) x 10 (11) mW (1) 2] and effective self-focusing performance [n(2) = (67 +/- 5) x 10 (18) 1, (13 +/- 3) x 10 (18) m(2) W (1) 2] in 1.02 x 10 (4) 1 and 1.05 x 10 (4) mol dm (3) 2 DMF solution separately. The values of the limiting threshold are also measured from the optical limiting experimental data. The heavy atom effect plays important role in the enhancement of optical non-linearities and optical limiting properties. (C) 2009 Elsevier B. V. All rights reserved.
学科主题	Chemistry, Inorganic & Nuclear ; Chemistry, Organic
URL标识	查看原文
语种	英语
WOS记录号	WOS:000269723700017
公开日期	2010-12-21
内容类型	期刊论文
源URL	[http://ir.qdio.ac.cn/handle/337002/2261]
专题	海洋研究所_海洋腐蚀与防护研究发展中心
作者单位	1.Qingdao Univ Sci & Technol, Key Lab Adv Mat, Qingdao 266042, Peoples R China 2.Chinese Acad Sci, Inst Oceanol, Qingdao 266071, Peoples R China
推荐引用方式 GB/T 7714	Liu, Fa-Qian,Li, Rong-Xun,Deng, Yue-Yi,et al. Studies on two coordination polymers [M(mu(4)-pz25dc)](n) (M = Cd or Zn, pz25dc=pyrazine-2,5-dicarboxylato) with three-dimensional pillared-layer three-nodal framework: Synthesis, structural characterization, strong optical non-linearities and optical limiting properties[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY,2009,694(22):3653-3659.
APA	Liu, Fa-Qian,Li, Rong-Xun,Deng, Yue-Yi,Li, Wei-Hua,Ding, Nai-Xiu,&Liu, Guang-Ye.(2009).Studies on two coordination polymers [M(mu(4)-pz25dc)](n) (M = Cd or Zn, pz25dc=pyrazine-2,5-dicarboxylato) with three-dimensional pillared-layer three-nodal framework: Synthesis, structural characterization, strong optical non-linearities and optical limiting properties.JOURNAL OF ORGANOMETALLIC CHEMISTRY,694(22),3653-3659.
MLA	Liu, Fa-Qian,et al."Studies on two coordination polymers [M(mu(4)-pz25dc)](n) (M = Cd or Zn, pz25dc=pyrazine-2,5-dicarboxylato) with three-dimensional pillared-layer three-nodal framework: Synthesis, structural characterization, strong optical non-linearities and optical limiting properties".JOURNAL OF ORGANOMETALLIC CHEMISTRY 694.22(2009):3653-3659.