Catalytic Conversion of Biomass-derived Carbohydrates into 5-Hydroxymethylfurfural using a Strong Solid Acid Catalyst in Aqueous gamma-Valerolactone

doi:10.15376/biores.11.3.5839-5853

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	Catalytic Conversion of Biomass-derived Carbohydrates into 5-Hydroxymethylfurfural using a Strong Solid Acid Catalyst in Aqueous gamma-Valerolactone
	Li, Wenzhi 1; Xu, Zhiping 2; Zhang, Tingwei 1; Li, Guojun 2; Jameel, Hasan 3; Chang, Hou-min 3; Ma, Longlong4
刊名	BIORESOURCES
	2016-08-01
卷号	11 期号:3 页码:5839-5853
关键词	Fructose 5-hydroxymethylfurfural Dehydration Gamma-valerolactone Ptsa-pom Catalyst
DOI	10.15376/biores.11.3.5839-5853
文献子类	Article
英文摘要	Selective conversion of biomass-derived carbohydrates into 5-hydroxy-methylfurfural (HMF) is of great significance for biomass conversion. In this study, a novel solid Bronsted acid was prepared simply by the copolymerization of paraformaldehyde and p-toluenesulfonic acid and then used to catalyze the conversion of various carbohydrates into HMF in.-valerolactone-water (GVL/H2O) reaction medium for the first time. The catalyst exhibited strong acidity, good water resistance, and high thermal stability. The present work focuses on the effects of various reaction parameters, including reaction temperature, time, water concentration, solvent, fructose level, and catalyst loading, on fructose dehydration. The catalyst exhibited excellent catalytic performance for HMF production from fructose in GVL and furnished a high HMF yield of 78.1% at 130 degrees C in 30 min. The recycling experiments suggested that the solid acid catalyst could be recycled at least seven times without a noticeable decrease in the catalytic activity. In addition, an attempt to study the one-step conversion of sucrose, glucose, and cellulose into HMF and furfural was performed using the same catalytic system.
WOS关键词	LIGNOCELLULOSIC BIOMASS ; SUSTAINABLE PLATFORM ; ORGANIC-SOLVENT ; IONIC LIQUIDS ; FRUCTOSE ; GLUCOSE ; DEHYDRATION ; EFFICIENT ; CELLULOSE ; HMF
语种	英语
WOS记录号	WOS:000384922400016
资助机构	Science and Technological Fund of Anhui Province for Outstanding Youth(1508085J01) ; National Basic Research Program of China(2012CB215302) ; National Key Technologies RD Program(2015BAD15B06) ; Key Programs of the Chinese Academy of Sciences(KGZD-EW-304-2)
内容类型	期刊论文
源URL	[http://ir.giec.ac.cn/handle/344007/14010]
专题	中国科学院广州能源研究所
作者单位	1.Univ Sci & Technol China, Dept Thermal Sci & Energy Engn, Hefei 230026, Peoples R China 2.Univ Sci & Technol China, Dept Chem, Hefei 230026, Peoples R China 3.North Carolina State Univ, Dept Forest Biomat, Raleigh, NC 27695 USA 4.Chinese Acad Sci, Guangzhou Inst Energy Convers, CAS Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China
推荐引用方式 GB/T 7714	Li, Wenzhi,Xu, Zhiping,Zhang, Tingwei,et al. Catalytic Conversion of Biomass-derived Carbohydrates into 5-Hydroxymethylfurfural using a Strong Solid Acid Catalyst in Aqueous gamma-Valerolactone[J]. BIORESOURCES,2016,11(3):5839-5853.
APA	Li, Wenzhi.,Xu, Zhiping.,Zhang, Tingwei.,Li, Guojun.,Jameel, Hasan.,...&Ma, Longlong.(2016).Catalytic Conversion of Biomass-derived Carbohydrates into 5-Hydroxymethylfurfural using a Strong Solid Acid Catalyst in Aqueous gamma-Valerolactone.BIORESOURCES,11(3),5839-5853.
MLA	Li, Wenzhi,et al."Catalytic Conversion of Biomass-derived Carbohydrates into 5-Hydroxymethylfurfural using a Strong Solid Acid Catalyst in Aqueous gamma-Valerolactone".BIORESOURCES 11.3(2016):5839-5853.