Oligomerization of Biomass Cracking Gas to Gasoline Distillates over Amorphous Silica-alumina

doi:10.7503/cjcu20160309

CORC > 广州能源研究所 > 中国科学院广州能源研究所 > 中国科学院广州能源研究所

	Oligomerization of Biomass Cracking Gas to Gasoline Distillates over Amorphous Silica-alumina
	Zhang Qian 1,2; Ding Mingyue1 ; Zhang Yulan 1,2; Li Yuping1 ; Wang Chenguang 1; Wang Tiejun1 ; Ma Longlong1
刊名	CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE
	2016-11-10
卷号	37 期号:11 页码:2060-2067
关键词	Biomass Cracking Gas Riched Light Olefin Olefins Oligomerization Amorphous Silica-alumina Fixed-bed Reactor
DOI	10.7503/cjcu20160309
文献子类	Article
英文摘要	The oligomerization performances of biomass cracking gas over amorphous silica-alumina(ASA) were investigated in a fixed bed in the region of 100-320 degrees C and 2.0-4.0 MPa. NH3-TPD, Py-IR, TG, SEM, BET and XRD were used to characterize the surface structures, acidity properties and carbon deposition of catalysts. The results showed that there were different degrees of acid amount loss and carbon deposition for ASA during oligomerization under different reaction conditions. The loss of Lewis acid amount decreased gra-dually with increasing temperature, and reached the minimum at 280 degrees C, and then begun to increase with continual increase of temperature. The increase of pressure is beneficial to reduce the Lewis acid loss. The change trend of carbon deposition was consistent with that of Lewis acid loss. During oligomerization, the conversion of light olefins and yield of gasoline range products increased gradually with the increase of temperature and pressure, and reached the maximum at 4.0 MPa and 280 degrees C. The conversions of ethylene, propylene and butylene reached 19.2%, 37.3% and 58.7%, respectively. The yield of gasoline range product reached 22.9%(molar fraction), and the selectivity of C5+ olefins reached 73.5%.
WOS关键词	ETHYLENE OLIGOMERIZATION ; CATALYTIC CRACKING ; ZEOLITE H-ZSM-5 ; NICKEL-COMPLEX ; LIGHT OLEFINS ; CONVERSION ; HYDROCARBONS ; DEACTIVATION ; METHANOL ; GROWTH
语种	英语
WOS记录号	WOS:000388831400018
资助机构	National Natural Science Foundation of China(51561145010 ; National Key Basic Research Program of China(2013CB228105) ; Science and Technology Planning Project of Guangdong Province, China(2013B010405012 ; U1362109) ; 2015A010106011 ; 2016A050502037)
内容类型	期刊论文
源URL	[http://ir.giec.ac.cn/handle/344007/14004]
专题	中国科学院广州能源研究所
作者单位	1.Chinese Acad Sci, Key Lab Renewable Energy, Guangzhou Inst Energy Convers, Guangdong Key Lab New & Renewable Energy Res & De, Guangzhou 510640, Guangdong, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
推荐引用方式 GB/T 7714	Zhang Qian,Ding Mingyue,Zhang Yulan,et al. Oligomerization of Biomass Cracking Gas to Gasoline Distillates over Amorphous Silica-alumina[J]. CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,2016,37(11):2060-2067.
APA	Zhang Qian.,Ding Mingyue.,Zhang Yulan.,Li Yuping.,Wang Chenguang.,...&Ma Longlong.(2016).Oligomerization of Biomass Cracking Gas to Gasoline Distillates over Amorphous Silica-alumina.CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,37(11),2060-2067.
MLA	Zhang Qian,et al."Oligomerization of Biomass Cracking Gas to Gasoline Distillates over Amorphous Silica-alumina".CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE 37.11(2016):2060-2067.