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Band gap modulated by electronic superlattice in blue phosphorene
Zhuang, Jincheng1,2; Liu, Chen3; Gao, Qian4; Liu, Yani1,2; Feng, Haifeng1,2; Xu, Xun1; Wang, Jiaou3; Zhao, Jijun5; Dou, Shi Xue1,2; Hu, Zhenpeng4
刊名Acs nano
2018-05-01
卷号12期号:5页码:5059-5065
关键词Blue phosphorene Band gap Electronic superlattice Arpes Stm Band folding
ISSN号1936-0851
DOI10.1021/acsnano.8b02953
通讯作者Du, yi(yi_du@uow.edu.au)
英文摘要Exploring stable two-dimensional materials with appropriate band gaps and high carrier mobility is highly desirable due to the potential applications in optoelectronic devices. here, the electronic structures of phosphorene on a au(111) substrate are investigated by scanning tunneling spectroscopy, angle-resolved photo emission spectroscopy (arpes), and density functional theory (dft) calculations. the substrate -induced phosphorene superstructure gives a superlattice potential, leading to a strong band folding effect of the sp band of au(111) on the band structure. the band gap could be clearly identified in the arpes results after examining the folded sp band. the value of the energy gap (similar to 1.1 ev) and the high charge carrier mobility comparable to that of black phosphorus, which is engineered by the tensile strain, are revealed by the combination of arpes results and dft calculations. furthermore, the phosphorene layer on the au(111) surface displays high surface inertness, leading to the absence of multilayer phosphorene. all these results suggest that the phosphorene on au(111) could be a promising candidate, not only for fundamental research but also for nanoelectronic and optoelectronic applications.
WOS关键词TOTAL-ENERGY CALCULATIONS ; WAVE BASIS-SET ; CRYSTAL-STRUCTURE ; BLACK PHOSPHORUS ; EFFICIENCY ; GERMANENE ; AU(111) ; GROWTH ; RED
WOS研究方向Chemistry ; Science & Technology - Other Topics ; Materials Science
WOS类目Chemistry, Multidisciplinary ; Chemistry, Physical ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary
语种英语
出版者AMER CHEMICAL SOC
WOS记录号WOS:000433404500107
内容类型期刊论文
URI标识http://www.corc.org.cn/handle/1471x/2177502
专题高能物理研究所
通讯作者Du, Yi
作者单位1.Univ Wollongong, AIIM, ISEM, Wollongong, NSW 2525, Australia
2.Beihang Univ, Dept Phys, BUAA UOW Joint Ctr, Beijing 100091, Peoples R China
3.Chinese Acad Sci, Inst High Energy Phys, Beijing Synchrotron Radiat Facil, Beijing 100049, Peoples R China
4.Nankai Univ, Sch Phys, Tianjin 300071, Peoples R China
5.Dalian Univ Technol, Minist Educ, Key Lab Mat Modificat Laser Ion & Electron Beams, Dalian 116024, Peoples R China
推荐引用方式
GB/T 7714
Zhuang, Jincheng,Liu, Chen,Gao, Qian,et al. Band gap modulated by electronic superlattice in blue phosphorene[J]. Acs nano,2018,12(5):5059-5065.
APA Zhuang, Jincheng.,Liu, Chen.,Gao, Qian.,Liu, Yani.,Feng, Haifeng.,...&Du, Yi.(2018).Band gap modulated by electronic superlattice in blue phosphorene.Acs nano,12(5),5059-5065.
MLA Zhuang, Jincheng,et al."Band gap modulated by electronic superlattice in blue phosphorene".Acs nano 12.5(2018):5059-5065.
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