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Gold functionalised attapulgite for discrimination of hydrogen peroxide and oxidising ions
Zhu, Dan1; Zhu, Wenfeng2; Wang, Weiwei1; Liu, Xiaoheng1
刊名Iet nanobiotechnology
2017-03-01
卷号11期号:2页码:200-204
ISSN号1751-8741
DOI10.1049/iet-nbt.2016.0006
通讯作者Liu, xiaoheng(xhliu@njust.edu.cn)
英文摘要Aiming to monitor hydrogen peroxide and oxidizing ions in aqueous circumstance, functionalized attapulgite [i.e. gold-modified attapulgite nanocomposites (au/atp ncs)] as peroxidase mimics were prepared by loading beta-cysteamine-capped gold nanoparticles onto attapulgite with the use of electrostatic interactions. as-prepared au/atp ncs were used for the detection of h2o2. the linear range and detection limit for h2o2 were determined by quantitative experiments emerging excellent stability and recyclability. the peroxidase-like activity of au/atp ncs could be expanded for the detection of some oxidative ions (fe3+ and ag+) was also been discovered. based on the absorption spectrum and steady-state kinetics, the mechanism for peroxidase mimic reaction is investigated. this work represents the first example of multitarget detection for molecule and cations (h2o2, fe3+ and ag+) using au/atp ncs as peroxidase enzyme mimics and holds a promise for future biomedical and analytical applications.
WOS关键词ARTIFICIAL ENZYMES ; GLUCOSE DETECTION ; AQUEOUS-SOLUTION ; NANOPARTICLES ; ADSORPTION ; OXIDATION ; MIMETICS ; OXIDASE
WOS研究方向Biochemistry & Molecular Biology ; Science & Technology - Other Topics
WOS类目Biochemical Research Methods ; Nanoscience & Nanotechnology
语种英语
出版者INST ENGINEERING TECHNOLOGY-IET
WOS记录号WOS:000399750500011
内容类型期刊论文
URI标识http://www.corc.org.cn/handle/1471x/2177452
专题高能物理研究所
通讯作者Liu, Xiaoheng
作者单位1.Nanjing Univ Sci & Technol, Key Lab Soft Chem & Funct Mat, Minist Educ, 200 Xiaolingwei St, Nanjing 210094, Jiangsu, Peoples R China
2.Chinese Acad Sci, Inst High Energy Phys, CAS Key Lab Biomed Effects Nanomat & Nanosafety, Beijing 100049, Peoples R China
推荐引用方式
GB/T 7714
Zhu, Dan,Zhu, Wenfeng,Wang, Weiwei,et al. Gold functionalised attapulgite for discrimination of hydrogen peroxide and oxidising ions[J]. Iet nanobiotechnology,2017,11(2):200-204.
APA Zhu, Dan,Zhu, Wenfeng,Wang, Weiwei,&Liu, Xiaoheng.(2017).Gold functionalised attapulgite for discrimination of hydrogen peroxide and oxidising ions.Iet nanobiotechnology,11(2),200-204.
MLA Zhu, Dan,et al."Gold functionalised attapulgite for discrimination of hydrogen peroxide and oxidising ions".Iet nanobiotechnology 11.2(2017):200-204.
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