Gold functionalised attapulgite for discrimination of hydrogen peroxide and oxidising ions | |
Zhu, Dan1; Zhu, Wenfeng2; Wang, Weiwei1; Liu, Xiaoheng1 | |
刊名 | Iet nanobiotechnology |
2017-03-01 | |
卷号 | 11期号:2页码:200-204 |
ISSN号 | 1751-8741 |
DOI | 10.1049/iet-nbt.2016.0006 |
通讯作者 | Liu, xiaoheng(xhliu@njust.edu.cn) |
英文摘要 | Aiming to monitor hydrogen peroxide and oxidizing ions in aqueous circumstance, functionalized attapulgite [i.e. gold-modified attapulgite nanocomposites (au/atp ncs)] as peroxidase mimics were prepared by loading beta-cysteamine-capped gold nanoparticles onto attapulgite with the use of electrostatic interactions. as-prepared au/atp ncs were used for the detection of h2o2. the linear range and detection limit for h2o2 were determined by quantitative experiments emerging excellent stability and recyclability. the peroxidase-like activity of au/atp ncs could be expanded for the detection of some oxidative ions (fe3+ and ag+) was also been discovered. based on the absorption spectrum and steady-state kinetics, the mechanism for peroxidase mimic reaction is investigated. this work represents the first example of multitarget detection for molecule and cations (h2o2, fe3+ and ag+) using au/atp ncs as peroxidase enzyme mimics and holds a promise for future biomedical and analytical applications. |
WOS关键词 | ARTIFICIAL ENZYMES ; GLUCOSE DETECTION ; AQUEOUS-SOLUTION ; NANOPARTICLES ; ADSORPTION ; OXIDATION ; MIMETICS ; OXIDASE |
WOS研究方向 | Biochemistry & Molecular Biology ; Science & Technology - Other Topics |
WOS类目 | Biochemical Research Methods ; Nanoscience & Nanotechnology |
语种 | 英语 |
出版者 | INST ENGINEERING TECHNOLOGY-IET |
WOS记录号 | WOS:000399750500011 |
内容类型 | 期刊论文 |
URI标识 | http://www.corc.org.cn/handle/1471x/2177452 |
专题 | 高能物理研究所 |
通讯作者 | Liu, Xiaoheng |
作者单位 | 1.Nanjing Univ Sci & Technol, Key Lab Soft Chem & Funct Mat, Minist Educ, 200 Xiaolingwei St, Nanjing 210094, Jiangsu, Peoples R China 2.Chinese Acad Sci, Inst High Energy Phys, CAS Key Lab Biomed Effects Nanomat & Nanosafety, Beijing 100049, Peoples R China |
推荐引用方式 GB/T 7714 | Zhu, Dan,Zhu, Wenfeng,Wang, Weiwei,et al. Gold functionalised attapulgite for discrimination of hydrogen peroxide and oxidising ions[J]. Iet nanobiotechnology,2017,11(2):200-204. |
APA | Zhu, Dan,Zhu, Wenfeng,Wang, Weiwei,&Liu, Xiaoheng.(2017).Gold functionalised attapulgite for discrimination of hydrogen peroxide and oxidising ions.Iet nanobiotechnology,11(2),200-204. |
MLA | Zhu, Dan,et al."Gold functionalised attapulgite for discrimination of hydrogen peroxide and oxidising ions".Iet nanobiotechnology 11.2(2017):200-204. |
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