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Impact of pyrolysis process on the chromium behavior of copr
Zhang, Dalei1; He, Shengbing1; Dai, Luwei1; Xie, Yaning2; Wu, Deyi1; Bu, Guanhua1; Peng, Kangjin1; Kong, Hainan1
刊名Journal of hazardous materials
2009-12-30
卷号172期号:2-3页码:1597-1601
关键词Pyrolysis Copr Sewage sludge Reduction
ISSN号0304-3894
DOI10.1016/j.jhazmat.2009.08.032
通讯作者Kong, hainan(hnkong@sjtu.edu.cn)
英文摘要The effect of pyrolysis process with sewage sludge on the chromium behavior of chromite ore processing residue (copr) was examined in this study. the behavior of chromium was characterized in term of chromium oxidation test, ph-static leaching tests, column leaching test and sequential extraction test. as a sequence of pyrolysis process, the cr(vi) in copr was effectively reduced from 5057 mg kg(-1) for untreated copr to 8.6 mg kg(-1) for treated copr at temperature over 600 degrees c, which is far below the new jersey department of environmental protection regulatory limit of 240 mg kg(-1). as a result, the amount of exchangeable and carbonate-bound cr fractions, the most mobile for the environment, were largely reduced. at the same time, the amount of the other three cr fractions which are much less mobile become augmented. ph static test showed that the chromium in the treated copr at pyrolysis temperature above 400 degrees c was quite stable at ph > 7. column study also indicated that only negligible amount of chromium of the treated copr at above 600 degrees c can be released by the acid rain. (c) 2009 elsevier b.v. all rights reserved.
WOS关键词SEWAGE-SLUDGE ; ORE ; REMEDIATION ; RESIDUE ; DISPOSAL
WOS研究方向Engineering ; Environmental Sciences & Ecology
WOS类目Engineering, Environmental ; Engineering, Civil ; Environmental Sciences
语种英语
出版者ELSEVIER SCIENCE BV
WOS记录号WOS:000271980800144
内容类型期刊论文
URI标识http://www.corc.org.cn/handle/1471x/2175951
专题高能物理研究所
通讯作者Kong, Hainan
作者单位1.Shanghai Jiao Tong Univ, Sch Environm Sci & Engn, Shanghai 200240, Peoples R China
2.Chinese Acad Sci, Beijing Synchrotron Radiat Facil, Beijing 100039, Peoples R China
推荐引用方式
GB/T 7714
Zhang, Dalei,He, Shengbing,Dai, Luwei,et al. Impact of pyrolysis process on the chromium behavior of copr[J]. Journal of hazardous materials,2009,172(2-3):1597-1601.
APA Zhang, Dalei.,He, Shengbing.,Dai, Luwei.,Xie, Yaning.,Wu, Deyi.,...&Kong, Hainan.(2009).Impact of pyrolysis process on the chromium behavior of copr.Journal of hazardous materials,172(2-3),1597-1601.
MLA Zhang, Dalei,et al."Impact of pyrolysis process on the chromium behavior of copr".Journal of hazardous materials 172.2-3(2009):1597-1601.
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