Selenium-catalyzed reductive carbonylation of 2-nitrophenols to 2-benzoxazolones

	Selenium-catalyzed reductive carbonylation of 2-nitrophenols to 2-benzoxazolones
	Wang, XF; Ling, G; Xue, Y; Lu, SW
刊名	european journal of organic chemistry
	2005-04-15
卷号	2005 期号:8 页码:1675-1679
关键词	carbonylation nitrophenols phase-transfer catalysis reduction selenium
通讯作者	陆世维
产权排序	1;1
英文摘要	2-benzoxazolones or 2-benzimidazolones are synthesized in moderate to good yields in the presence of a base (koh, naoh, koac, net3, dbu) at atmospheric pressure or under a high pressure of co by one-pot reductive carbonylation of 2-nitrophenols or 2-nitroanihne in the presence of selenium as catalyst. besides the effect of base, the effects of solvent and temperature on the reaction were investigated at high or atmospheric pressure. contrasting results were obtained for 2-benzoxazolones or 2-benzimidazolone at high and atmospheric pressures. moreover, phase-transfer catalysis was exhibited. ((c) wiley-vch verlag gmbh & co. kgaa, 69451 weinheim, germany, 2005).
WOS标题词	science & technology ; physical sciences
类目[WOS]	chemistry, organic
研究领域[WOS]	chemistry
关键词[WOS]	carbon-monoxide ; oxidative carbonylation ; cyclic ureas ; assisted carbonylation ; aromatic-amines ; deoxygenation ; nitrobenzene ; derivatives ; diamines ; co
收录类别	SCI
原文出处	true
语种	英语
WOS记录号	WOS:000228785100024
公开日期	2010-11-30
内容类型	期刊论文
源URL	[http://159.226.238.44/handle/321008/93145]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
作者单位	Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116011, Liaoning, Peoples R China
推荐引用方式 GB/T 7714	Wang, XF,Ling, G,Xue, Y,et al. Selenium-catalyzed reductive carbonylation of 2-nitrophenols to 2-benzoxazolones[J]. european journal of organic chemistry,2005,2005(8):1675-1679.
APA	Wang, XF,Ling, G,Xue, Y,&Lu, SW.(2005).Selenium-catalyzed reductive carbonylation of 2-nitrophenols to 2-benzoxazolones.european journal of organic chemistry,2005(8),1675-1679.
MLA	Wang, XF,et al."Selenium-catalyzed reductive carbonylation of 2-nitrophenols to 2-benzoxazolones".european journal of organic chemistry 2005.8(2005):1675-1679.