Cycloheptyl-fused NNO-ligands as electronically modifiable supports for M(II) (M=Co, Fe) chloride precatalysts; probing performance in ethylene oligo-/polymerization | |
Sun WH(孙文华); Sun WH(孙文华)2,3,4; Liang, Tongling2; Huang, Chuanbing2,4; Gregory A. Solan1,2; Du, Shizhen2; Wang, Zheng2,4; Chantsalnyam Bariashir2,4 | |
刊名 | Journal of Polymer Science Part A: Polymer Chemistry |
2017 | |
卷号 | 55期号:24页码:3980-3989 |
关键词 | Coordination Polymerization Α-imino-α′-oxo-2 Metal-organic Catalysts 3:5 Oligomers 6-bis(Pentamethylene)Pyridine Polyethylene |
ISSN号 | 0887-624X |
DOI | 10.1002/pola.28767 |
英文摘要 | The N,N,O-cobalt(II), [2,3-{C4H8C(NAr)}:5,6-{C4H8C(O)}C5HN]CoCl2 (Ar = 2,6-(CHPh2)2-4-MeC6H2 Co1, 2,6-(CHPh2)2-4-EtC6H2 Co2, 2,6-(CHPh2)2-4-ClC6H2 Co3, 2,6-(CHPh2)2-4-FC6H2 Co4) and N,N,O-iron(II) complexes, [2,3-{C4H8C(NAr)}:5,6-{C4H8C(O)}C5HN]FeCl2 (Ar = 2,6-(CHPh2)2-4-MeC6H2 Fe1, 2,6-(CHPh2)2-4-EtC6H2 Fe2, 2,6-(CHPh2)2-4-ClC6H2 Fe3, 2,6-(CHPh2)2-4-FC6H2 Fe4), each containing one sterically enhanced but electronically modifiable N-2,6-dibenzhydryl-4-R2-phenyl group, have been prepared by a one-pot template approach using ,′-dioxo-2,3:5,6-bis(pentamethylene)pyridine, the corresponding aniline along with the respective cobalt or iron salt in acetic acid. Distorted square pyramidal geometries are a feature of the molecular structures of Co1–Co4. Upon activation with MAO or MMAO, Co1–Co4 show good activities (up to 2.2 × 105 g mol−1(Co) h−1) affording short chain oligomers (C4–C30) with good -olefin selectivity. By contrast, Fe1–Fe4, in the presence of MMAO, displayed moderate activities (up 10.9 × 104 g(PE) mol−1(Fe) h−1) for ethylene polymerization forming low-molecular-weight linear polymers (up to 13.0 kg mol−1) incorporating saturated n-propyl and i-butyl chain ends. For both cobalt and iron, the precatalysts incorporating the more electron withdrawing 4-R2-substituents [Cl (Co3/Fe3), F (Co4/Fe4)] deliver the best catalytic activities, while with cobalt, these types of substituents additionally broaden the oligomeric distribution. |
学科主题 | 物理化学与绿色催化 |
语种 | 英语 |
WOS记录号 | WOS:000414322000004 |
资助机构 | the National Natural Science Foundation of China (Nos. 21374123;U1362204);CB is grateful to the CAS-TWAS president’s fellowship. GAS thanks the Chinese Academy of Sciences for a Visiting Fellowship |
内容类型 | 期刊论文 |
源URL | [http://ir.licp.ac.cn/handle/362003/22742] |
专题 | 兰州化学物理研究所_OSSO国家重点实验室 |
通讯作者 | Sun WH(孙文华); Gregory A. Solan |
作者单位 | 1.Department of Chemistry, University of Leicester, University Road, Leicester LE1 7RH, United Kingdom 2.Key Laboratory of Engineering Plastics and Beijing National Laboratory for Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China 3.State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, China 4.CAS Research/Education Center for Excellence in Molecular Sciences and International School, University of Chinese Academy of Sciences, Beijing 100049, China |
推荐引用方式 GB/T 7714 | Sun WH,Sun WH,Liang, Tongling,et al. Cycloheptyl-fused NNO-ligands as electronically modifiable supports for M(II) (M=Co, Fe) chloride precatalysts; probing performance in ethylene oligo-/polymerization[J]. Journal of Polymer Science Part A: Polymer Chemistry,2017,55(24):3980-3989. |
APA | 孙文华.,Sun WH.,Liang, Tongling.,Huang, Chuanbing.,Gregory A. Solan.,...&Chantsalnyam Bariashir.(2017).Cycloheptyl-fused NNO-ligands as electronically modifiable supports for M(II) (M=Co, Fe) chloride precatalysts; probing performance in ethylene oligo-/polymerization.Journal of Polymer Science Part A: Polymer Chemistry,55(24),3980-3989. |
MLA | 孙文华,et al."Cycloheptyl-fused NNO-ligands as electronically modifiable supports for M(II) (M=Co, Fe) chloride precatalysts; probing performance in ethylene oligo-/polymerization".Journal of Polymer Science Part A: Polymer Chemistry 55.24(2017):3980-3989. |
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