Solid polymer electrolyte based on thermoplastic polyurethane and its application in all-solid-state lithium ion batteries
Yu, Ran1; Bao, Jun-Jie1; Chen, Tian-Tian1; Zou, Bang-Kun1; Wen, Zhao-Yin2; Guo, Xiang-Xin2; Chen, Chun-Hua1
刊名Solid State Ionics
2017
卷号309页码:15-21
ISSN号01672738
DOI10.1016/j.ssi.2017.06.013
英文摘要In this paper a new kind of solid polymer electrolyte (SPE) based on thermoplastic polyurethane (TPU) is fabricated. With the dispersion of Li7La3Zr2O12powders, the lithium ionic conductivity of the SPE can be improved effectively. By optimizing the amount of Li7La3Zr2O12, an ionic conductivity of 8.89 × 10− 5S cm− 1at 80 °C is achieved. X-ray diffraction and scanning electron microscopy are employed to analyze the crystallinity and microstructure of the SPE samples. The all-solid-state lithium ion cells with the TPU-based SPE as solid electrolyte and LiFePO4as active cathode material are assembled through a simple blade-coating method. Such all-solid-state cells exhibit a specific capacity (160 mAh g− 1) comparable with the traditional cells using organic liquid electrolyte at the current density of 5.3 μA cm− 2. To further investigate the electrochemical performances of the all-solid-state cells, the cyclic voltammetry and galvanostatic cycling are also performed and analyzed. © 2017 Elsevier B.V.
内容类型期刊论文
源URL[http://ir.sic.ac.cn/handle/331005/25811]  
专题中国科学院上海硅酸盐研究所
作者单位1.CAS Key Laboratory of Materials for Energy Conversions, Department of Materials Science and Engineering& Collaborative Innovation Center of Suzhou Nano Science and Technology, University of Science and Technology of China, Hefei; Anhui; 230026, China;
2.Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai; 200050, China
推荐引用方式
GB/T 7714
Yu, Ran,Bao, Jun-Jie,Chen, Tian-Tian,et al. Solid polymer electrolyte based on thermoplastic polyurethane and its application in all-solid-state lithium ion batteries[J]. Solid State Ionics,2017,309:15-21.
APA Yu, Ran.,Bao, Jun-Jie.,Chen, Tian-Tian.,Zou, Bang-Kun.,Wen, Zhao-Yin.,...&Chen, Chun-Hua.(2017).Solid polymer electrolyte based on thermoplastic polyurethane and its application in all-solid-state lithium ion batteries.Solid State Ionics,309,15-21.
MLA Yu, Ran,et al."Solid polymer electrolyte based on thermoplastic polyurethane and its application in all-solid-state lithium ion batteries".Solid State Ionics 309(2017):15-21.
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