Compound Defects and Thermoelectric Properties of Self-Charge Compensated Skutterudites SeyCo4Sb12-xSex

doi:10.1021/acsami.7b05887

	Compound Defects and Thermoelectric Properties of Self-Charge Compensated Skutterudites SeyCo4Sb12-xSex
	Wan, Shun 1,2; Huang, Xiangyang 1; Qiu, Pengfei 1; Shi, Xun 1; Chen, Lidong 1
刊名	ACS Applied Materials and Interfaces
	2017
卷号	9 期号:27 页码:22713-22724
ISSN号	19448244
DOI	10.1021/acsami.7b05887
英文摘要	In the past two decades, many studies have focused on the effects of electropositive guest fillers on the electrical and thermal transport properties in CoSb3-based skutterudites. Recently, some electronegative elements such as S, Se, Cl, and Br have been filled into the voids in CoSb3with a small amount of n-type dopant Te on the Sb sites. In this report, self-charge compensated skutterudites SeyCo4Sb12-xSex(0 3with a solubility limit around 0.6. The Se content has little effect on bandgap. Similar to Ga dual-site occupied GayCo4Sb12-xGax(y = 2x), a typical semiconducting electrical property with a low carrier concentration as well as a large Seebeck coefficient is observed. A correlation between the large Seebeck coefficient and the carrier scattering mechanism has been proposed. In addition, a largely reduced room temperature lattice thermal conductivity is obtained with a minimum value of 2.1 Wm-1K-1for Se0.2Co4Sb11.6Se0.4. The effects of Se on lattice thermal conductivity and filler resonant frequency are discussed. © 2017 American Chemical Society.
内容类型	期刊论文
源URL	[http://ir.sic.ac.cn/handle/331005/25878]
专题	中国科学院上海硅酸盐研究所
作者单位	1.State Key Laboratory of High Performance Ceramics and Superfine Microstructure, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai; 200050, China; 2.University of Chinese Academy of Sciences, Beijing; 100049, China
推荐引用方式 GB/T 7714	Wan, Shun,Huang, Xiangyang,Qiu, Pengfei,et al. Compound Defects and Thermoelectric Properties of Self-Charge Compensated Skutterudites SeyCo4Sb12-xSex[J]. ACS Applied Materials and Interfaces,2017,9(27):22713-22724.
APA	Wan, Shun,Huang, Xiangyang,Qiu, Pengfei,Shi, Xun,&Chen, Lidong.(2017).Compound Defects and Thermoelectric Properties of Self-Charge Compensated Skutterudites SeyCo4Sb12-xSex.ACS Applied Materials and Interfaces,9(27),22713-22724.
MLA	Wan, Shun,et al."Compound Defects and Thermoelectric Properties of Self-Charge Compensated Skutterudites SeyCo4Sb12-xSex".ACS Applied Materials and Interfaces 9.27(2017):22713-22724.