Facile triethanolamine-assisted combustion synthesized layered LiNi1/3Co1/3Mn1/3O2 cathode materials with enhanced electrochemical performance for lithium-ion batteries

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	Facile triethanolamine-assisted combustion synthesized layered LiNi1/3Co1/3Mn1/3O2 cathode materials with enhanced electrochemical performance for lithium-ion batteries
	Zeng, Jinbo 1,2; Hai, Chunxi 1,2; Ren, Xiufeng 1,2; Li, Xiang 1,2; Shen, Yue 1,2; Dong, Ouyang 1,2; Zhang, Lijuan 1,2,3; Sun, Yanxia 1,2,3; Ma, Luxiang 1,2,3; Zhang, Xinxing 1,2,3
刊名	JOURNAL OF ALLOYS AND COMPOUNDS
	2018-02-25
卷号	735 页码:1977-1985
关键词	Triethanolamine-assisted Combustion Method Layered Lini1/3co1/3mn1/3o2 Cathode Materials
文献子类	Article
英文摘要	The present study introduces a facile triethanolamine-assisted combustion method, wherein stoichiometric hydrate transition metal acetate with and without the addition of triethanolamine (TEA) were dissolved and mixed uniformly in deionized water and heated to burn. The ashes were then grinded and calcinated to synthesize layered LiNi1/3Co1/3Mn1/3O2 cathode materials. The structure, morphology, and electrochemical performance of two kinds of LiNi1/3Co1/3Mn1/3O2 materials were investigated and compared systematically. The results indicate that the sample with TEA possesses smaller particles and exhibits less aggregation and a better hexagonal layered structure. On the contrary, the sample with TEA exhibits lower polarization, a better cycling ability, a significantly improved rate performance, and better electronic conductivity. The enhanced electronic conductivity and electrochemical performance may be ascribed to a higher combustion enthalpy and better dispersion in the solvent following the introduction of TEA. This simple synthetic strategy presents a promising synthetic model for the enhancement of electrochemical performance cathode materials for lithium-ion batteries. (C) 2017 Elsevier B.V. All rights reserved.
WOS关键词	HIGH CUTOFF VOLTAGE ; COATED LINI1/3CO1/3MN1/3O2 ; HEAT-TREATMENT ; SURFACE MODIFICATION ; CYCLING PERFORMANCE ; RATE CAPABILITY ; LI ; LINI1/3MN1/3CO1/3O2 ; MICROSPHERES ; LINI0.6MN0.2CO0.2O2
WOS研究方向	Chemistry ; Materials Science ; Metallurgy & Metallurgical Engineering
语种	英语
WOS记录号	WOS:000418518600240
内容类型	期刊论文
源URL	[http://ir.isl.ac.cn/handle/363002/6372]
专题	青海盐湖研究所_青海盐湖研究所知识仓储青海盐湖研究所_盐湖资源与化学实验室
作者单位	1.Chinese Acad Sci, Qinghai Inst Salt Lakes, Key Lab Comprehens & Highly Efficient Utilizat Sa, 18th Xinning Rd, Xining 810008, Qinghai, Peoples R China 2.Key Lab Salt Lake Resources Chem Qinghai Prov, Xining 810008, Qinghai, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
推荐引用方式 GB/T 7714	Zeng, Jinbo,Hai, Chunxi,Ren, Xiufeng,et al. Facile triethanolamine-assisted combustion synthesized layered LiNi1/3Co1/3Mn1/3O2 cathode materials with enhanced electrochemical performance for lithium-ion batteries[J]. JOURNAL OF ALLOYS AND COMPOUNDS,2018,735:1977-1985.
APA	Zeng, Jinbo.,Hai, Chunxi.,Ren, Xiufeng.,Li, Xiang.,Shen, Yue.,...&Zhou, Yuan.(2018).Facile triethanolamine-assisted combustion synthesized layered LiNi1/3Co1/3Mn1/3O2 cathode materials with enhanced electrochemical performance for lithium-ion batteries.JOURNAL OF ALLOYS AND COMPOUNDS,735,1977-1985.
MLA	Zeng, Jinbo,et al."Facile triethanolamine-assisted combustion synthesized layered LiNi1/3Co1/3Mn1/3O2 cathode materials with enhanced electrochemical performance for lithium-ion batteries".JOURNAL OF ALLOYS AND COMPOUNDS 735(2018):1977-1985.