Lithium difluoro(sulfato)borate as a novel electrolyte salt for high-temperature lithium-ion batteries
Li, Shiyou1; Zhao, Wei1; Cui, Xiaoling1; Zhang, Hongming1; Wang, Xiuxiu1; Zhong, Wanxiang1; Feng, Huixia1; Liu, Haining2
刊名ELECTROCHIMICA ACTA
2014-05-20
卷号129页码:327-333
关键词Lithium Difluoro(Sulfato)Borate Electrolyte Thermal Stability Elevated Temperature Lithium-ion Battery
文献子类Article
英文摘要High-temperature electrochemical behaviors of the novel salt named lithium difluoro(sulfato)borate (LiBF2SO4) were studied by employment of ethylene carbonate (EC) and dimethyl carbonate (DMC) as mixed solvents. In Li/MCMB (mesophase carbon microbeads) cells at 80 degrees C, LiBF2SO4-EC/DMC electrolyte favourably facilitates the formation of a thermal stable, effective and conductive interface film on the surface of carbonaceous anode. Besides, in LiFePO4/Li cells at 80 degrees C, LiBF2SO4-EC/DMC electrolyte exerts several advantages, such as stable cycling performance, low polarization resistance, and good rate performance. It suggests that LiBF2SO4 is an excellent candidate salt for advanced high-temperature lithium-ion batteries. (C) 2014 Elsevier Ltd. All rights reserved.
WOS关键词ELECTROCHEMICAL PERFORMANCES ; GRAPHITE ; SULFOLANE ; CARBONATE ; LIPF6 ; CELLS ; LAYER
WOS研究方向Electrochemistry
语种英语
WOS记录号WOS:000336466100042
内容类型期刊论文
源URL[http://ir.isl.ac.cn/handle/363002/5668]  
专题青海盐湖研究所_青海盐湖研究所知识仓储
青海盐湖研究所_盐湖资源与化学实验室
中国科学院青海盐湖研究所
作者单位1.Lanzhou Univ Technol, Coll Petrochem Technol, Lanzhou 730050, Peoples R China
2.Chinese Acad Sci, Qinghai Inst Salt Lakes, Key Lab Salt Lake Resources & Chem, Xining 810008, Peoples R China
推荐引用方式
GB/T 7714
Li, Shiyou,Zhao, Wei,Cui, Xiaoling,et al. Lithium difluoro(sulfato)borate as a novel electrolyte salt for high-temperature lithium-ion batteries[J]. ELECTROCHIMICA ACTA,2014,129:327-333.
APA Li, Shiyou.,Zhao, Wei.,Cui, Xiaoling.,Zhang, Hongming.,Wang, Xiuxiu.,...&Liu, Haining.(2014).Lithium difluoro(sulfato)borate as a novel electrolyte salt for high-temperature lithium-ion batteries.ELECTROCHIMICA ACTA,129,327-333.
MLA Li, Shiyou,et al."Lithium difluoro(sulfato)borate as a novel electrolyte salt for high-temperature lithium-ion batteries".ELECTROCHIMICA ACTA 129(2014):327-333.
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