Formation of C-C and C-O bonds via solvothermal in situ metal-ligand reaction: Synthesis and crystal structures of two novel nickel(II) complexes supported by in situ generated polydentate Schiff base ligands | |
Lei, Tao1,2; Gao, Qian1; Chen, Wen-Qian1; Chen, Yan-Mei1; Liu, Wei1; Yang, Shu-Min1; Chen, Wei-Wei1; Li, Wu2; Li, Yahong1,3 | |
刊名 | INORGANIC CHEMISTRY COMMUNICATIONS |
2013-04-01 | |
卷号 | 30页码:92-96 |
关键词 | Crystal Structures Nickel(Ii) Complexes In Situ Metal-ligand Reaction Carbon-carbon Bond Making Carbon-oxygen Bond Formation |
文献子类 | Article |
英文摘要 | Under solvothermal conditions, complexes Ni(HL2) (1) and Ni(L3)center dot MeOH (2 center dot MeOH) (H(3)L2=N-(2-(2-hydroxybenzylideneamino)-1-(2-hydroxyphenyl)-2-(pyridin-2-yl)ethyl)picolinamide; H(2)L3=1-(pyridin-2-yl)prop-1-ene-1,2-diyl)bis(azan-1-yl-1-ylidene)bis((methan-1-yl-1-ylidene)diphenol) have been synthesized from the reaction of Ni(CH3COO)(2)center dot 4H(2)O with 2-((pyridin-2-ylmethyleneamino)methyl)phenol (HL1) at 70 and 90 degrees C, respectively. The complexes were characterized by X-ray single crystal diffraction, IR spectroscopy, and elemental analysis. The plausible mechanisms for the formation of H(3)L2 and H(3)L3 via solvothermal in situ metal-ligand reactions were proposed. (C) 2013 Elsevier B.V. All rights reserved. |
WOS关键词 | METAL/LIGAND REDOX REACTIONS ; COORDINATION POLYMERS ; HYDROTHERMAL SYNTHESIS ; PHYSICAL-PROPERTIES ; COPPER(I) ; HYDROXYLATION ; CLUSTERS |
WOS研究方向 | Chemistry |
语种 | 英语 |
WOS记录号 | WOS:000317446600022 |
内容类型 | 期刊论文 |
源URL | [http://ir.isl.ac.cn/handle/363002/4454] |
专题 | 青海盐湖研究所_青海盐湖研究所知识仓储 中国科学院青海盐湖研究所 |
作者单位 | 1.Soochow Univ, Coll Chem Chem Engn & Mat Sci, Key Lab Organ Synth Jiangsu Prov, Suzhou 215123, Peoples R China 2.Chinese Acad Sci, Qinghai Inst Salt Lakes, CAS Key Lab Salt Lake Resources & Chem, Xining 810008, Peoples R China 3.Lanzhou Univ, State Key Lab Appl Organ Chem, Lanzhou 730000, Peoples R China |
推荐引用方式 GB/T 7714 | Lei, Tao,Gao, Qian,Chen, Wen-Qian,et al. Formation of C-C and C-O bonds via solvothermal in situ metal-ligand reaction: Synthesis and crystal structures of two novel nickel(II) complexes supported by in situ generated polydentate Schiff base ligands[J]. INORGANIC CHEMISTRY COMMUNICATIONS,2013,30:92-96. |
APA | Lei, Tao.,Gao, Qian.,Chen, Wen-Qian.,Chen, Yan-Mei.,Liu, Wei.,...&Li, Yahong.(2013).Formation of C-C and C-O bonds via solvothermal in situ metal-ligand reaction: Synthesis and crystal structures of two novel nickel(II) complexes supported by in situ generated polydentate Schiff base ligands.INORGANIC CHEMISTRY COMMUNICATIONS,30,92-96. |
MLA | Lei, Tao,et al."Formation of C-C and C-O bonds via solvothermal in situ metal-ligand reaction: Synthesis and crystal structures of two novel nickel(II) complexes supported by in situ generated polydentate Schiff base ligands".INORGANIC CHEMISTRY COMMUNICATIONS 30(2013):92-96. |
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