Facile Synthesis of Au/Pd Nano-dumbells for Catalytic Reduction of p-Nitrophenol

doi:10.15541/jim20170146

	Facile Synthesis of Au/Pd Nano-dumbells for Catalytic Reduction of p-Nitrophenol
	Yin Yue-Yue ; Yang Yong ; Zhang Liang-Zhu ; Li Yong-Sheng ; Ma Yun-Feng ; Yang Li-Li ; Huang Zheng-Ren
刊名	JOURNAL OF INORGANIC MATERIALS
	2018
卷号	33 期号:1 页码:19
关键词	nano-dumbbells seed-meditated method p-nitrophenol
ISSN号	1000-324X
DOI	10.15541/jim20170146
英文摘要	Au nanorods (Au NRs) with good monodispersity and uniform aspect ratio were prepared via seed-meditated method. Au/Pd nano-dumbbells (Au/Pd NDs) were synthesized by using H2PdCl4\ as precursor, hexadecyl trimethyl ammonium chloride (CTAC) as soft template, Ag+ as structure-directing agent and ascorbic acid as reduction agent to modify Au NRs. Structure and morphology of the samples were characterized by transmission electron microscope (TEM), energy dispersive spectrometer (EDS) and ultraviolet-visible-near infrared spectrophotometry (UV-Vis-NIR). The formation mechanism of Au/Pd NDs were discussed. The results of Au/Pd NDs samples demonstrated that lots of poly-crystalline Pd particles were deposited onto two ends of Au nanorods selectively to form dumbbell-like structure. The dumbbell size can be continuously tuned by adjusting the molar ratio of AA and H2PdCl4. The experiments of reduction of p-nitrophenol by NaBH4 to p-aminophenol indicate that the sample with good dispersibility and large number of total catalytic active sites of Pd nanoparticles has high catalytic performance. Adding 0.04 mg/mL Au/Pd NDs with suitable Pd particles size (20.7 nm) show excellent catalytic activity (rate constant 0.44 min(-1)), indicating it is useful for reducing p-nitrophenol.
学科主题	Materials Science, Ceramics
出版者	SCIENCE PRESS
WOS记录号	WOS:000425504900004
资助机构	National Natural Science Foundation of China (51471182) ; Shanghai International Science & Technology Cooperation Program (17520711700) ; National Natural Science Foundation of China (51471182) ; Shanghai International Science & Technology Cooperation Program (17520711700)
内容类型	期刊论文
源URL	[http://ir.sic.ac.cn/handle/331005/24585]
专题	中国科学院上海硅酸盐研究所
作者单位	1.[Yin Yue-Yue 2.East China Univ Sci & Technol, Sch Mat Sci & Engn, Shanghai 200237, Peoples R China 3.[Yang Yong 4.Zhang Liang-Zhu 5.Ma Yun-Feng 6.Yang Li-Li 7.Chinese Acad Sci, Shanghai Inst Ceram, State Key Lab High Performance Ceram & Superfine, Shanghai 200050, Peoples R China
推荐引用方式 GB/T 7714	Yin Yue-Yue,Yang Yong,Zhang Liang-Zhu,et al. Facile Synthesis of Au/Pd Nano-dumbells for Catalytic Reduction of p-Nitrophenol[J]. JOURNAL OF INORGANIC MATERIALS,2018,33(1):19, 26.
APA	Yin Yue-Yue.,Yang Yong.,Zhang Liang-Zhu.,Li Yong-Sheng.,Ma Yun-Feng.,...&Huang Zheng-Ren.(2018).Facile Synthesis of Au/Pd Nano-dumbells for Catalytic Reduction of p-Nitrophenol.JOURNAL OF INORGANIC MATERIALS,33(1),19.
MLA	Yin Yue-Yue,et al."Facile Synthesis of Au/Pd Nano-dumbells for Catalytic Reduction of p-Nitrophenol".JOURNAL OF INORGANIC MATERIALS 33.1(2018):19.