Metal-free synthesis of fulleropyrrolidin-2-ols: a novel reaction of [60]fullerene with amines and 2,2-disubstituted acetaldehydes

doi:10.1039/c8ob01903g

	Metal-free synthesis of fulleropyrrolidin-2-ols: a novel reaction of [60]fullerene with amines and 2,2-disubstituted acetaldehydes
	Alamry, Khalid A.1; Asiri, Abdullah M.1; Liu, Chao-Yang 2; Liu, Li 3,4; Yang, Fei 3,4; Li, Fa-Bao 3,4; Wang, Hui-Juan 2; Zhang, Meng 3,4; Huang, Gang 3,4
刊名	ORGANIC & BIOMOLECULAR CHEMISTRY
	2018-11-07
卷号	16 期号:41 页码:7648-7656
ISSN号	1477-0520
DOI	10.1039/c8ob01903g
英文摘要	A series of scarce fulleropyrrolidin-2-ols were synthesized by the facile one-step reaction of [60] fullerene with inexpensive and readily accessible amines and 2,2-disubstituted acetaldehydes without the addition of valuable metal salts in moderate yields, comparable to those for most monoadducts reported previously. This strategy exhibits a broad substrate scope and excellent functional group tolerance. A plausible reaction pathway for the formation of fulleropyrrolidin-2-ols is proposed to elucidate the above reaction process.
资助项目	National Natural Science Foundation of China[21102041] ; National Natural Science Foundation of China[21671061] ; Scientific Research Foundation of Education Commission of Hubei Province[D20161007] ; Innovation and Entrepreneurship Training Program for Undergraduates of Hubei Province[201710512044] ; Innovation and Entrepreneurship Training Program for Undergraduates of Hubei Province[201810512046]
WOS关键词	ONE-STEP REACTION ; FERRIC PERCHLORATE ; MEDIATED SYNTHESIS ; 1,3-DIPOLAR CYCLOADDITION ; POLYHYDROXYLATED C-60 ; MAGNESIUM PERCHLORATE ; AROMATIC-ALDEHYDES ; CHIRAL FULLERENES ; FUSED FULLERENE ; ACID ESTERS
WOS研究方向	Chemistry
语种	英语
出版者	ROYAL SOC CHEMISTRY
WOS记录号	WOS:000448344400015
资助机构	National Natural Science Foundation of China ; Scientific Research Foundation of Education Commission of Hubei Province ; Innovation and Entrepreneurship Training Program for Undergraduates of Hubei Province ; National Natural Science Foundation of China ; Scientific Research Foundation of Education Commission of Hubei Province ; Innovation and Entrepreneurship Training Program for Undergraduates of Hubei Province ; National Natural Science Foundation of China ; Scientific Research Foundation of Education Commission of Hubei Province ; Innovation and Entrepreneurship Training Program for Undergraduates of Hubei Province ; National Natural Science Foundation of China ; Scientific Research Foundation of Education Commission of Hubei Province ; Innovation and Entrepreneurship Training Program for Undergraduates of Hubei Province
内容类型	期刊论文
源URL	[http://ir.wipm.ac.cn/handle/112942/13169]
专题	中国科学院武汉物理与数学研究所
通讯作者	Liu, Chao-Yang; Li, Fa-Bao
作者单位	1.King Abdulaziz Univ, Dept Chem, Fac Sci, Jeddah 21589, Saudi Arabia 2.Chinese Acad Sci, Wuhan Inst Phys & Math, Wuhan Ctr Magnet Resonance, State Key Lab Magnet Resonance & Atom & Mol Phys, Wuhan 430071, Hubei, Peoples R China 3.Hubei Univ, Sch Chem & Chem Engn, Wuhan 430062, Hubei, Peoples R China 4.Hubei Univ, Hubei Collaborat Innovat Ctr Adv Organ Chem Mat, Key Lab Synth & Applicat Organ Funct Mol, Key Lab Green Preparat & Applicat Funct Mat,Minis, Wuhan 430062, Hubei, Peoples R China
推荐引用方式 GB/T 7714	Alamry, Khalid A.,Asiri, Abdullah M.,Liu, Chao-Yang,et al. Metal-free synthesis of fulleropyrrolidin-2-ols: a novel reaction of [60]fullerene with amines and 2,2-disubstituted acetaldehydes[J]. ORGANIC & BIOMOLECULAR CHEMISTRY,2018,16(41):7648-7656.
APA	Alamry, Khalid A..,Asiri, Abdullah M..,Liu, Chao-Yang.,Liu, Li.,Yang, Fei.,...&Huang, Gang.(2018).Metal-free synthesis of fulleropyrrolidin-2-ols: a novel reaction of [60]fullerene with amines and 2,2-disubstituted acetaldehydes.ORGANIC & BIOMOLECULAR CHEMISTRY,16(41),7648-7656.
MLA	Alamry, Khalid A.,et al."Metal-free synthesis of fulleropyrrolidin-2-ols: a novel reaction of [60]fullerene with amines and 2,2-disubstituted acetaldehydes".ORGANIC & BIOMOLECULAR CHEMISTRY 16.41(2018):7648-7656.