An eco-friendly and efficient binary catalyst system of superbases and amino acids was developed for the synthesis of cyclic carbonates from epoxides and CO2 under metal-free and halide-free conditions. Among the various amino acids and superbases systems tested, the L-histidine/1,8-diazabicyclo[5.4.0]-undec-7-ene (DBU) system achieved the highest conversion of propylene oxide and selectivity of propylene carbonate. The effect of various reaction parameters was evaluated. A possible catalyst mechanism for L-histidine synergized with DBU in the ring opening of epoxide and DBU introduced CO2 activation. The process herein represents a green, simple, and cost-effective route for the chemical fixation of CO2 into cyclic carbonates.