Synthesis, characterization and activity evaluation of Cu-based catalysts derived from layered double hydroxides (LDHs) for DeNO(x) reaction
Zhang, Yu-sheng1,2; Li, Changming1; Yu, Chao2; Tran, Tuyetsuong1; Guo, Feng1; Yang, Yunquan2; Yu, Jian1; Xu, Guangwen1
刊名CHEMICAL ENGINEERING JOURNAL
2017-12-15
卷号330期号:DEC页码:1082-1090
关键词Catalytic Filter Deno(x) Ldhs In-situ Growth
ISSN号1385-8947
DOI10.1016/j.cej.2017.08.044
文献子类Article
英文摘要

Catalytic filter for DeNO(x) reaction composed of practical ceramic filter and catalytic active component enables simultaneous removal of dusts and NOx and therefore is of great potential for industrial application. To find out catalytically active components for DeNO(x) reaction and concurrently which can be grown on ceramic filter by an in-situ method, the Cu-based catalysts derived from LDHs precursor with different promoters (Co, Ni, Zn, Mg) were synthesized. The results of catalytic activity evaluation showed Zn is the most suitable promoter. Then, the effect of the Cu/Zn ratio on the catalytic performance was examined. It was found that the (CuxZny)(2)Al-MMO with an Cu/Zn ratio of 4 exhibited the maximum NOx conversion of 80% at 240 degrees C and a NH3/NO ratio of 0.8. The addition of Zn could weaken the catalytic oxidation of ammonia (NH3-SCO) and then improve turnover frequency (TOF) of NOx reduction per Cu atom. The characterizations of the TEM and H-2-N2O titration to catalysts reveal that the addition of Zn helps the dispersity of CuO on the surface of the support. The H-2-TPR results further demonstrates that the added Zn species facilitate the reducibility of CuO species at low temperature. At last, in-situ growth of Cu-Zn-Al-LDHs on a practical ceramic filter for DeNO(x) reaction was first successfully carried out and the resulted catalytic filter showed a reasonably high DeNO(x) activity and strong bonding strength between catalyst and filter.

WOS关键词COMBINED PARTICLE SEPARATION ; CERAMIC FILTER CANDLE ; IN-SITU SYNTHESIS ; SELECTIVE REDUCTION ; DIMETHYL OXALATE ; ETHYLENE-GLYCOL ; LOW-TEMPERATURE ; NO REDUCTION ; MG-AL ; REMOVAL
WOS研究方向Engineering
语种英语
WOS记录号WOS:000414083300108
资助机构Science and Technology Service Network Initiative of China(KFJ-SW-STS-149) ; International Science and Technology Cooperation Program of China(2016YFE0128300) ; Natural Science and Foundation of China(21601192) ; Japan Society for the Promotion of Science (JSPS)(P15758)
内容类型期刊论文
源URL[http://ir.ipe.ac.cn/handle/122111/23377]  
专题过程工程研究所_多相复杂系统国家重点实验室
作者单位1.Chinese Acad Sci, Inst Proc Engn, State Key Lab Multiphase Complex Syst, Beijing 100190, Peoples R China
2.Xiangtan Univ, Sch Chem Engn, Xiangtan, Hunan 411105, Peoples R China
推荐引用方式
GB/T 7714
Zhang, Yu-sheng,Li, Changming,Yu, Chao,et al. Synthesis, characterization and activity evaluation of Cu-based catalysts derived from layered double hydroxides (LDHs) for DeNO(x) reaction[J]. CHEMICAL ENGINEERING JOURNAL,2017,330(DEC):1082-1090.
APA Zhang, Yu-sheng.,Li, Changming.,Yu, Chao.,Tran, Tuyetsuong.,Guo, Feng.,...&Xu, Guangwen.(2017).Synthesis, characterization and activity evaluation of Cu-based catalysts derived from layered double hydroxides (LDHs) for DeNO(x) reaction.CHEMICAL ENGINEERING JOURNAL,330(DEC),1082-1090.
MLA Zhang, Yu-sheng,et al."Synthesis, characterization and activity evaluation of Cu-based catalysts derived from layered double hydroxides (LDHs) for DeNO(x) reaction".CHEMICAL ENGINEERING JOURNAL 330.DEC(2017):1082-1090.
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