Glycerol carbonate synthesis from glycerol and dimethyl carbonate using guanidine ionic liquids

doi:10.1016/j.cjche.2017.06.025

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	Glycerol carbonate synthesis from glycerol and dimethyl carbonate using guanidine ionic liquids
	Wang, Xingxing 1,2; Zhang, Peng 1; Cui, Penglei 1; Cheng, Weiguo 1; Zhang, Suojiang 1
刊名	CHINESE JOURNAL OF CHEMICAL ENGINEERING
	2017-09-01
卷号	25 期号:9 页码:1182-1186
关键词	Guanidine-based Ionic Liquids Glycerol Carbonate Transesterification
ISSN号	1004-9541
DOI	10.1016/j.cjche.2017.06.025
文献子类	Article
英文摘要	A large number of surplus glycerol from the biodiesel production can be used as renewable feedstock to produce glycerol carbonate. In this paper, a series of guanidine-based ionic liquids were synthesized to catalyze the transesterification of glycerol and dimethyl carbonate. The tunable basicity and the anion-cation cooperative effect were responsible for the obtained results. The [TMG][TFE] showed the best activity turnover frequency (TOF) of 1754.0 h(-1), glycerol (GL) conversion of 91.8%, glycerol carbonate (GC) selectivity of 95.5%) at 80 degrees C with 0.1 mol% catalyst for 30 min. The reaction mechanism of the transesterification was also proposed. (C) 2017 The Chemical Industry and Engineering Society of China, and Chemical Industry Press. All rights reserved.
WOS关键词	MIXED-OXIDE CATALYST ; TRANSESTERIFICATION ; EFFICIENT ; DIOXIDE ; 1,1,3,3-TETRAMETHYLGUANIDINE ; 1,2-CARBONATE ; GLYCIDOL ; CAPTURE ; SOLVENT ; ACID
WOS研究方向	Engineering
语种	英语
WOS记录号	WOS:000411395200008
资助机构	National Natural Sciences Foundation of China(91434107 ; National Key Projects for Fundamental Research and Development of China(2016YFB0600903) ; 21506232)
内容类型	期刊论文
源URL	[http://ir.ipe.ac.cn/handle/122111/23249]
专题	过程工程研究所_多相复杂系统国家重点实验室
作者单位	1.Chinese Acad Sci, Beijing Key Lab Ion Liquids Clean Proc, Inst Proc Engn, Key Lab Green Proc Engn,State Key Lab Multiphase, Beijing 100190, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
推荐引用方式 GB/T 7714	Wang, Xingxing,Zhang, Peng,Cui, Penglei,et al. Glycerol carbonate synthesis from glycerol and dimethyl carbonate using guanidine ionic liquids[J]. CHINESE JOURNAL OF CHEMICAL ENGINEERING,2017,25(9):1182-1186.
APA	Wang, Xingxing,Zhang, Peng,Cui, Penglei,Cheng, Weiguo,&Zhang, Suojiang.(2017).Glycerol carbonate synthesis from glycerol and dimethyl carbonate using guanidine ionic liquids.CHINESE JOURNAL OF CHEMICAL ENGINEERING,25(9),1182-1186.
MLA	Wang, Xingxing,et al."Glycerol carbonate synthesis from glycerol and dimethyl carbonate using guanidine ionic liquids".CHINESE JOURNAL OF CHEMICAL ENGINEERING 25.9(2017):1182-1186.