Pyrolysis of Huadian Oil Shale in an Infrared Heating Reactor
Siramard, Somprasong1,2; Bumnan, Yutthasin1,2; Lai, Dengguo1,2; Xu, Guangwen1
刊名ENERGY & FUELS
2017-07-01
卷号31期号:7页码:6996-7003
ISSN号0887-0624
DOI10.1021/acs.energyfuels.7b00964
文献子类Article
英文摘要

Pyrolysis of Huadian oil shale was investigated in a newly designed shallow fixed bed reactor mounted with infrared heating to clarify the pyrolysis behavior at different heating rates and pyrolysis temperatures under minimized secondary reactions to volatiles in an oil shale bed. The maximum shale oil recovery was obtained under the proper conditions of a heating rate of 0.5 degrees C/s, a pyrolysis temperature of about 550 degrees C, a reduced reaction pressure (0.6 atm in this work), and for a single layer oil shale bed. The highest shale oil yield under such conditions was close to 100% of the Fischer Assay oil yield (11.10 wt % of dry basis). For the adopted infrared-heating reactor, increasing the heating, rate decreased the shale oil yield but increased the gas production. The total hydrogen in volatile products including shale oil and pyrolysis gas increased with raising the heating rate, and the total volatile production was higher for the infrared quick heating pyrolysis (heating rate: 25 degrees C/s) than that for the Fischer Assay. The shale oil from the infrared quick heating pyrolysis had also more light fraction. Experiment also found that pyrolyzing the multilayer oil shale bed lowered the shale oil yield in comparison with the pyrolysis of a single-layer material bed. Thus, adopting a single-layer oil shale bed, low infrared heating rates, and reduced reaction pressures obviously suppressed the secondary reactions toward volatiles to have consequently high shale oil yield. High infrared heating rate facilitated volatile and hydrogen production but led to more serious secondary reactions to lower the shale oil yield.

WOS关键词Rapid Pyrolysis ; Products Yield ; Particle-size ; Grain-size ; Fixed-bed ; Coal ; Evolution ; Catalyst ; Goynuk
WOS研究方向Energy & Fuels ; Engineering
语种英语
WOS记录号WOS:000406356600034
资助机构National Basic Research Program of China(2014CB744303) ; National Natural Science Foundation(91534125) ; CAS-TWAS
内容类型期刊论文
源URL[http://ir.ipe.ac.cn/handle/122111/23172]  
专题过程工程研究所_多相复杂系统国家重点实验室
作者单位1.Chinese Acad Sci, Inst Proc Engn, State Key Lab Multiphase Complex Syst, Beijing 100190, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
推荐引用方式
GB/T 7714
Siramard, Somprasong,Bumnan, Yutthasin,Lai, Dengguo,et al. Pyrolysis of Huadian Oil Shale in an Infrared Heating Reactor[J]. ENERGY & FUELS,2017,31(7):6996-7003.
APA Siramard, Somprasong,Bumnan, Yutthasin,Lai, Dengguo,&Xu, Guangwen.(2017).Pyrolysis of Huadian Oil Shale in an Infrared Heating Reactor.ENERGY & FUELS,31(7),6996-7003.
MLA Siramard, Somprasong,et al."Pyrolysis of Huadian Oil Shale in an Infrared Heating Reactor".ENERGY & FUELS 31.7(2017):6996-7003.
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