Controlled Synthesis of Heterostructured SnO2-CuO Composite Hollow Microspheres as Efficient Cu-Based Catalysts for the Rochow Reaction

doi:10.3390/catal8040144

	Controlled Synthesis of Heterostructured SnO2-CuO Composite Hollow Microspheres as Efficient Cu-Based Catalysts for the Rochow Reaction
	Liu, Hezhi 1,2; Ji, Yongjun 2; Zou, Xiujing 1; Li, Jing 2; Zhang, Yu 2; Wang, Xueguang 1; Zhong, Ziyi 3; Su, Fabing 2,4
刊名	CATALYSTS
	2018-04-01
卷号	8 期号:4 页码:12
关键词	heterostructure hollow composite microsphere synergistic effect Rochow reaction
ISSN号	2073-4344
DOI	10.3390/catal8040144
英文摘要	In this work, we report the design and synthesis of a series of heterostructured SnO2-CuO hollow microspherical catalysts (H-SnO2(x)-CuO, x is the weight ratio of Sn/Cu) for the Rochow reaction. The microspherical catalysts with nanosheets and nanoparticles as building blocks were prepared by a facile one-pot hydrothermal method coupled with calcination. When tested for the Rochow reaction, the prepared H-SnO2(0.2)-CuO composite exhibited higher dimethyldichlorosilane selectivity (88.2%) and Si conversion (36.7%) than the solid CuO, hollow CuO and other H-SnO2(x)-CuO microspherical samples, because in the former there is a stronger synergistic interaction between CuO and SnO2.
资助项目	National Natural Science Foundation of China[21506224]
WOS关键词	REDUCTION REACTION ; METHYL-CHLORIDE ; METHYLCHLOROSILANES ; COPPER ; PERFORMANCE ; MECHANISM ; SILICON ; CO ; OXIDATION ; KINETICS
WOS研究方向	Chemistry
语种	英语
出版者	MDPI
WOS记录号	WOS:000435186400021
资助机构	National Natural Science Foundation of China
内容类型	期刊论文
源URL	[http://ir.ipe.ac.cn/handle/122111/24897]
专题	中国科学院过程工程研究所
通讯作者	Ji, Yongjun; Wang, Xueguang; Su, Fabing
作者单位	1.Shanghai Univ, Sch Mat Sci & Engn, State Key Lab Adv Special Steel, Shanghai 200072, Peoples R China 2.Chinese Acad Sci, Inst Proc Engn, State Key Lab Multiphase Complex Syst, Beijing 100190, Peoples R China 3.ASTAR, Inst Chem & Engn Sci, 1 Pesek Rd, Singapore 627833, Singapore 4.Shenyang Univ Chem Technol, Inst Ind Chem & Energy Technol, Shenyang 110142, Liaoning, Peoples R China
推荐引用方式 GB/T 7714	Liu, Hezhi,Ji, Yongjun,Zou, Xiujing,et al. Controlled Synthesis of Heterostructured SnO2-CuO Composite Hollow Microspheres as Efficient Cu-Based Catalysts for the Rochow Reaction[J]. CATALYSTS,2018,8(4):12.
APA	Liu, Hezhi.,Ji, Yongjun.,Zou, Xiujing.,Li, Jing.,Zhang, Yu.,...&Su, Fabing.(2018).Controlled Synthesis of Heterostructured SnO2-CuO Composite Hollow Microspheres as Efficient Cu-Based Catalysts for the Rochow Reaction.CATALYSTS,8(4),12.
MLA	Liu, Hezhi,et al."Controlled Synthesis of Heterostructured SnO2-CuO Composite Hollow Microspheres as Efficient Cu-Based Catalysts for the Rochow Reaction".CATALYSTS 8.4(2018):12.