A new approach to thiazoloisoindigo and derivatives using a lithium tetramethylpiperidine promoted cyclization to thiazoloisatin

doi:10.1039/c7QO00841D

CORC > 青岛生物能源与过程研究所 > 中国科学院青岛生物能源与过程研究所 > 生物基及仿生高分子材料团队

	A new approach to thiazoloisoindigo and derivatives using a lithium tetramethylpiperidine promoted cyclization to thiazoloisatin
	Chenchen Li, Huanrui Zhang, Samuel Mirie, Jiawei Peng, Mian Cai, Xiao Wang, Zhenggang Lan and Xiaobo Wan; Xiao Wang and Xiaobo Wan
刊名	Org. Chem. Front
	2017-10-23
期号	1 页码:1
DOI	10.1039/c7QO00841D
文献子类	Article
英文摘要	Brominated thiazoloisoindigo was synthesized for the first time from thiazoloisatin, which was obtained via an unprecedented nucleophilic cyclization strategy. Thiazoloisoindigo was shown to exhibit a deeper LUMO energy level than isoindigo and thienoisoindigo, which makes it a potential building block for n-type semiconductors. Moreover, brominated thiazoloisoindigo is sensitive toward nucleophilic attack, and its reaction with aniline resulted in an unexpectedly much more stable acceptor with a LUMO energy level as low as −3.82 eV
WOS记录号	WOS:000424012100017
内容类型	期刊论文
源URL	[http://ir.qibebt.ac.cn/handle/337004/9927]
专题	青岛生物能源与过程研究所_生物基及仿生高分子材料团队
通讯作者	Xiao Wang and Xiaobo Wan
作者单位	CAS Key Laboratory of Bio-based Materials, Qingdao Institute of Bioenergy & Bioprocess Technology, Chinese Academy of Sciences
推荐引用方式 GB/T 7714	Chenchen Li, Huanrui Zhang, Samuel Mirie, Jiawei Peng, Mian Cai, Xiao Wang, Zhenggang Lan and Xiaobo Wan,Xiao Wang and Xiaobo Wan. A new approach to thiazoloisoindigo and derivatives using a lithium tetramethylpiperidine promoted cyclization to thiazoloisatin[J]. Org. Chem. Front,2017(1):1.
APA	Chenchen Li, Huanrui Zhang, Samuel Mirie, Jiawei Peng, Mian Cai, Xiao Wang, Zhenggang Lan and Xiaobo Wan,&Xiao Wang and Xiaobo Wan.(2017).A new approach to thiazoloisoindigo and derivatives using a lithium tetramethylpiperidine promoted cyclization to thiazoloisatin.Org. Chem. Front(1),1.
MLA	Chenchen Li, Huanrui Zhang, Samuel Mirie, Jiawei Peng, Mian Cai, Xiao Wang, Zhenggang Lan and Xiaobo Wan,et al."A new approach to thiazoloisoindigo and derivatives using a lithium tetramethylpiperidine promoted cyclization to thiazoloisatin".Org. Chem. Front .1(2017):1.