Pyrolysis kinetic analysis of the three pseudocomponents of biomass-cellulose, hemicellulose and lignin | |
Chen, Tianju; Li, Lingyue; Zhao, Ruidong; Wu, Jinhu | |
刊名 | JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY |
2017-06-01 | |
卷号 | 128期号:3页码:1825-1832 |
关键词 | Pyrolysis Biomass Kinetic Analysis Pseudocomponent Sinusoidally Modulated Temperature Method |
DOI | 10.1007/s10973-016-6040-3 |
文献子类 | Article |
英文摘要 | The pyrolysis kinetic analysis of the three pseudocomponents of biomass, namely cellulose, hemicellulose and lignin, were investigated using a thermogravimetric (TG) analyzer. The multi-peaks method was used to fit the Gaussian distribution model of DTG curves. The activation energies of three pseudocomponents pyrolysis were evaluated using sinusoidally modulated temperature method. The results showed that the multi-peaks methods can fit the DTG curves of cellulose, hemicellulose and lignin successfully. There was only one reaction stage for the pyrolysis of cellulose and hemicelluloses. There were two reaction stages for the pyrolysis of lignin. The average E was 112.6, 162.8 and 156.8 kJ mol(-1) for cellulose, hemicellulose and lignin, respectively. |
WOS关键词 | BIO-OIL ; ACTIVATION-ENERGIES ; MODULATED THERMOGRAVIMETRY ; LIGNOCELLULOSIC BIOMASS ; STRAW PYROLYSIS ; REACTION MODEL ; DECOMPOSITION ; TEMPERATURE ; BIOCHAR ; REACTOR |
WOS研究方向 | Thermodynamics ; Chemistry |
语种 | 英语 |
WOS记录号 | WOS:000401349800054 |
资助机构 | National Natural Science Foundation of China(51406220) ; Shanxi Province Coal-based Key Technology Research and Development Program(MD 2014-03) |
内容类型 | 期刊论文 |
源URL | [http://ir.qibebt.ac.cn/handle/337004/9609] |
专题 | 青岛生物能源与过程研究所_热化学转化事业部 |
作者单位 | Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc, Key Lab Biofuels, 189 Songling Rd, Qingdao 266101, Peoples R China |
推荐引用方式 GB/T 7714 | Chen, Tianju,Li, Lingyue,Zhao, Ruidong,et al. Pyrolysis kinetic analysis of the three pseudocomponents of biomass-cellulose, hemicellulose and lignin[J]. JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY,2017,128(3):1825-1832. |
APA | Chen, Tianju,Li, Lingyue,Zhao, Ruidong,&Wu, Jinhu.(2017).Pyrolysis kinetic analysis of the three pseudocomponents of biomass-cellulose, hemicellulose and lignin.JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY,128(3),1825-1832. |
MLA | Chen, Tianju,et al."Pyrolysis kinetic analysis of the three pseudocomponents of biomass-cellulose, hemicellulose and lignin".JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY 128.3(2017):1825-1832. |
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