Chemical looping reforming of toluene as a biomass tar model compound over two types of oxygen carriers: 2CuO-2NiO/Al2O3 and CaFe2O4

doi:10.1016/j.fuel.2018.02.164

CORC > 青岛生物能源与过程研究所 > 中国科学院青岛生物能源与过程研究所 > 热化学转化事业部

	Chemical looping reforming of toluene as a biomass tar model compound over two types of oxygen carriers: 2CuO-2NiO/Al2O3 and CaFe2O4
	Wang, Zhiqi 1; Zhu, Min 1; He, Tao 1; Zhang, Jinzhi 1; Wu, Jingli 1; Tian, Hanjing 2; Wu, Jinhu 1
刊名	FUEL
	2018-06-15
卷号	222 页码:375-384
关键词	Biomass Gasification Tar Chemical Looping Reforming Toluene Oxygen Carriers
ISSN号	0016-2361
DOI	10.1016/j.fuel.2018.02.164
文献子类	Article
英文摘要	Chemical looping reforming/gasification of toluene, the model compound representing biomass tar, was studied by using two oxygen carriers, 2CuO-2NiO/Al2O3 (molar ratio) and CaFe2O4. Their reaction performances were evaluated in a TG-FTIR and a laboratory-scale fixed bed reactor. The active lattice oxygen of the 2CuO-2NiO/Al2O3 oxygen carrier demonstrated excellent reactivity and completely oxidized toluene to CO2 at 600-700 degrees C, while the fixed bed reactor data indicated that 2CuO-2NiO/Al2O3 oxygen carrier could catalyze the cracking of toluene to produce H-2 after loss of lattice oxygen. The CaFe2O4 oxygen carrier exhibited a good performance of chemical looping partial oxidation of toluene to CO and H-2 with a fairly high reactivity. Over CaFe2O4 oxygen carrier, the CO and H-2 dominated reaction products in the temperature range of 800-900 degrees C except at the startup stage. Catalytic cracking of toluene by CaFe2O4 to produce H-2 was also observed after partial loss of lattice oxygen. Stable performance of CaFe2O4 with high reactivity to syngas (CO and H-2) was demonstrated during a 3cyle test in the fixed bed reactor. After reduction of action with toluene, scanning electron microscopy (SEM) and X-ray diffraction (XRD) indicated that 2CuO-2NiO/Al2O3 was reduced to metallic copper and nickel with the mixture of NiAl2O4, and CaFe2O4 was reduced to metallic iron and CaO. In summary, two oxygen carriers displayed high toluene conversion at the beginning stage and the conversion of toluene increased to about 100% in the subsequent stage.
WOS关键词	SYNTHESIS GAS GENERATION ; OF-THE-ART ; COAL-GASIFICATION ; PRODUCER GAS ; LIQUID FUELS ; OXIDES ; CATALYST ; HYDROGEN ; METHANE ; ELIMINATION
WOS研究方向	Energy & Fuels ; Engineering
语种	英语
出版者	ELSEVIER SCI LTD
WOS记录号	WOS:000429422800038
资助机构	National Key R&D Program of China(2016YFE0108400) ; NSF-NSFC collaborative research(1511818) ; China Postdoctoral Science Foundation(2017M612368)
内容类型	期刊论文
源URL	[http://ir.qibebt.ac.cn/handle/337004/10795]
专题	青岛生物能源与过程研究所_热化学转化事业部
通讯作者	Wang, Zhiqi; Wu, Jinhu
作者单位	1.Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, Key Lab Biofuels, Qingdao 266101, Peoples R China 2.West Virginia Univ, Dept Chem Engn, Morgantown, WV 26505 USA
推荐引用方式 GB/T 7714	Wang, Zhiqi,Zhu, Min,He, Tao,et al. Chemical looping reforming of toluene as a biomass tar model compound over two types of oxygen carriers: 2CuO-2NiO/Al2O3 and CaFe2O4[J]. FUEL,2018,222:375-384.
APA	Wang, Zhiqi.,Zhu, Min.,He, Tao.,Zhang, Jinzhi.,Wu, Jingli.,...&Wu, Jinhu.(2018).Chemical looping reforming of toluene as a biomass tar model compound over two types of oxygen carriers: 2CuO-2NiO/Al2O3 and CaFe2O4.FUEL,222,375-384.
MLA	Wang, Zhiqi,et al."Chemical looping reforming of toluene as a biomass tar model compound over two types of oxygen carriers: 2CuO-2NiO/Al2O3 and CaFe2O4".FUEL 222(2018):375-384.