Synthesis of 2-AryI-5-alkyl-fulleropyrrolidines: Metal-Free-Mediated Reaction of [60]Fullerene with Aromatic Aldehydes and Inactive Primary Amines

doi:10.1021/acs.joc.7b01507

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	Synthesis of 2-AryI-5-alkyl-fulleropyrrolidines: Metal-Free-Mediated Reaction of [60]Fullerene with Aromatic Aldehydes and Inactive Primary Amines
	Liu, Chao-Yang 3; Asiri, Abdullah M.4; Wang, Hui-Juan 3; Li, Fa-Bao 1,2; Zhong, Xin-Xin 1,2; Zhang, Meng 1,2; Huang, Yong-Shun 1,2; Liu, Li 1,2; Alamry, Khalid A.4
刊名	JOURNAL OF ORGANIC CHEMISTRY
	2017-08-18
卷号	82 期号:16 页码:8617-8627
DOI	10.1021/acs.joc.7b01507
文献子类	Article
英文摘要	The metal-free-mediated thermal reaction of [60]fullerene with aromatic aldehydes and inactive primary amines bearing electron-donating groups at the alpha-position afforded a series of 2-aryl-5-alkyl-fulleropyrtolidines, including the scarce 27 aryl-5-benzyl-fulleropyrrolidines as a mixture of cis and trans isomers. With rare exceptions, the mixture of, cis, and trans isomers could be easily isolated by column chromatography, with a preference of cis isomers as Major products. A plausible mechanism for the formation of fulleropyrrolidines is also proposed.
WOS关键词	ONE-STEP REACTION ; FERRIC PERCHLORATE ; 1,3-DIPOLAR CYCLOADDITION ; FULLERENE DERIVATIVES ; AZOMETHINE YLIDES ; FACILE ACCESS ; ACID ESTERS ; FULLEROPYRROLIDINES ; C-60 ; FUNCTIONALIZATION
WOS研究方向	Chemistry
语种	英语
WOS记录号	WOS:000408285500028
资助机构	National Natural Science Foundation of China(21102041 ; National Natural Science Foundation of China(21102041 ; Scientific Research Foundation of Education Commission of Hubei Province(D20161007) ; Scientific Research Foundation of Education Commission of Hubei Province(D20161007) ; Innovation and Entrepreneurship Training Program for Undergraduates of Hubei Province(201610512054) ; Innovation and Entrepreneurship Training Program for Undergraduates of Hubei Province(201610512054) ; 21671061) ; 21671061) ; National Natural Science Foundation of China(21102041 ; National Natural Science Foundation of China(21102041 ; Scientific Research Foundation of Education Commission of Hubei Province(D20161007) ; Scientific Research Foundation of Education Commission of Hubei Province(D20161007) ; Innovation and Entrepreneurship Training Program for Undergraduates of Hubei Province(201610512054) ; Innovation and Entrepreneurship Training Program for Undergraduates of Hubei Province(201610512054) ; 21671061) ; 21671061)
内容类型	期刊论文
源URL	[http://ir.wipm.ac.cn/handle/112942/11330]
专题	武汉物理与数学研究所_高技术创新与发展中心
作者单位	1.Hubei Univ, Hubei Collaborat Innovat Ctr Adv Organ Chem Mat, Minist Educ, Key Lab Synth & Applicat Organ Funct Mol, Wuhan 430062, Hubei, Peoples R China 2.Hubei Univ, Sch Chem & Chem Engn, Wuhan 430062, Hubei, Peoples R China 3.Chinese Acad Sci, Wuhan Inst Phys & Math, Wuhan Ctr Magnet Resonance, State Key Lab Magnet Resonance & Atom & Mol Phys, Wuhan 430071, Hubei, Peoples R China 4.King Abdulaziz Univ, Dept Chem, Fac Sci, Jeddah 21589, Saudi Arabia
推荐引用方式 GB/T 7714	Liu, Chao-Yang,Asiri, Abdullah M.,Wang, Hui-Juan,et al. Synthesis of 2-AryI-5-alkyl-fulleropyrrolidines: Metal-Free-Mediated Reaction of [60]Fullerene with Aromatic Aldehydes and Inactive Primary Amines[J]. JOURNAL OF ORGANIC CHEMISTRY,2017,82(16):8617-8627.
APA	Liu, Chao-Yang.,Asiri, Abdullah M..,Wang, Hui-Juan.,Li, Fa-Bao.,Zhong, Xin-Xin.,...&Alamry, Khalid A..(2017).Synthesis of 2-AryI-5-alkyl-fulleropyrrolidines: Metal-Free-Mediated Reaction of [60]Fullerene with Aromatic Aldehydes and Inactive Primary Amines.JOURNAL OF ORGANIC CHEMISTRY,82(16),8617-8627.
MLA	Liu, Chao-Yang,et al."Synthesis of 2-AryI-5-alkyl-fulleropyrrolidines: Metal-Free-Mediated Reaction of [60]Fullerene with Aromatic Aldehydes and Inactive Primary Amines".JOURNAL OF ORGANIC CHEMISTRY 82.16(2017):8617-8627.