A Hierarchical Bipyridine-Constructed Framework for Highly Efficient Carbon Dioxide Capture and Catalytic Conversion

doi:10.1002/cssc.201601375

CORC > 武汉物理与数学研究所 > 中国科学院武汉物理与数学研究所 > 磁共振应用研究部

	A Hierarchical Bipyridine-Constructed Framework for Highly Efficient Carbon Dioxide Capture and Catalytic Conversion
	Dai, Zhifeng 1,3; Sun, Qi 1,3; Liu, Xiaolong 2; Guo, Liping 4; Li, Jixue 6; Pan, Shuxiang 1,3; Bian, Chaoqun 1,3; Deng, Feng 2; Xiao, Feng-Shou 1,3; Wang, Liang 1,3
刊名	CHEMSUSCHEM
	2017-03-22
卷号	10 期号:6 页码:1186-1192
关键词	Carbon Dioxide Fixation Cycloaddition Heterogeneous Catalysis Nitrogen Heterocycles Polymers
DOI	10.1002/cssc.201601375
文献子类	Article
英文摘要	As a C-1 feedstock, CO2 has the potential to be uniquely highly economical in both a chemical and a financial sense. Porous materials bearing particular binding and active sites that can capture and convert CO2 simultaneously are promising candidates for CO2 utilization. In this work, a bipyridine-constructed polymer featuring a high surface area, a hierarchical porous structure, and excellent stability was synthesized through free-radical polymerization. After metalation, the resultant catalysts exhibited superior activities in comparison with those of their homogeneous counterparts in the cycloaddition of CO2 to epoxides. The high performance of the heterogeneous catalysts originates from cooperative effects between the CO2-philic polymer and the embedded metal species. In addition, the catalysts showed excellent stabilities and are readily recyclable; thus, they are promising for practical utilization for the conversion of CO2 into value-added chemicals.
WOS关键词	METAL-ORGANIC FRAMEWORKS ; CO2 CAPTURE ; CYCLIC CARBONATES ; HETEROGENEOUS CATALYSTS ; AMBIENT CONDITIONS ; MICROPOROUS POLYMER ; IONIC LIQUID ; EPOXIDES ; CYCLOADDITION ; ADSORPTION
WOS研究方向	Chemistry
语种	英语
WOS记录号	WOS:000398182800019
资助机构	National Natural Science Foundation of China(21273197 ; National Natural Science Foundation of China(21273197 ; National High-Tech Research and Development program of China(2013AA065301) ; National High-Tech Research and Development program of China(2013AA065301) ; 21333009 ; 21333009 ; 21203165 ; 21203165 ; 21422306) ; 21422306) ; National Natural Science Foundation of China(21273197 ; National Natural Science Foundation of China(21273197 ; National High-Tech Research and Development program of China(2013AA065301) ; National High-Tech Research and Development program of China(2013AA065301) ; 21333009 ; 21333009 ; 21203165 ; 21203165 ; 21422306) ; 21422306)
内容类型	期刊论文
源URL	[http://ir.wipm.ac.cn/handle/112942/10884]
专题	武汉物理与数学研究所_磁共振应用研究部
作者单位	1.Zhejiang Univ, Key Lab Appl Chem Zhejiang Prov, Hangzhou 310028, Zhejiang, Peoples R China 2.Chinese Acad Sci, Wuhan Inst Phys & Math, State Key Lab Magnet Resonance & Atom & Mol Phys, Wuhan 430071, Peoples R China 3.Zhejiang Univ, Dept Chem, Hangzhou 310028, Zhejiang, Peoples R China 4.Zhejiang Normal Univ, Coll Chem & Life Sci, Jinhua 321004, Peoples R China 5.Zhejiang Normal Univ, Inst Phys Chem, Jinhua 321004, Peoples R China 6.Zhejiang Univ, Electron Microscopy Ctr, Hangzhou 310027, Zhejiang, Peoples R China
推荐引用方式 GB/T 7714	Dai, Zhifeng,Sun, Qi,Liu, Xiaolong,et al. A Hierarchical Bipyridine-Constructed Framework for Highly Efficient Carbon Dioxide Capture and Catalytic Conversion[J]. CHEMSUSCHEM,2017,10(6):1186-1192.
APA	Dai, Zhifeng.,Sun, Qi.,Liu, Xiaolong.,Guo, Liping.,Li, Jixue.,...&Zhao, Leihong.(2017).A Hierarchical Bipyridine-Constructed Framework for Highly Efficient Carbon Dioxide Capture and Catalytic Conversion.CHEMSUSCHEM,10(6),1186-1192.
MLA	Dai, Zhifeng,et al."A Hierarchical Bipyridine-Constructed Framework for Highly Efficient Carbon Dioxide Capture and Catalytic Conversion".CHEMSUSCHEM 10.6(2017):1186-1192.