The role of EDTA on rutile flotation using Al3+ ions as an activator | |
Xiao, W; Fang, CJ; Wang, J; Liang, QN; Cao, P; Wang, XX; Zhang, LJ; Qiu, GZ; Hu, J | |
刊名 | RSC ADVANCES
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2018 | |
卷号 | 8期号:9页码:4872-4880 |
关键词 | Sulfide Minerals Double-layer Adsorption Salt Ilmenite Titanium Behavior Gradient |
ISSN号 | 2046-2069 |
DOI | 10.1039/c7ra10576b |
文献子类 | 期刊论文 |
英文摘要 | Rutile is a relatively stable mineral, due to its weakly specific adsorption to collectors. The development and application of a high efficiency and low-toxicity activator is the main challenge in rutile flotation. In this study, Al3+ ions and EDTA (ethylene diamine tetraacetic acid) as mixed activators were investigated using micro-flotation tests. The results of the micro-flotation tests showed that the flotation recovery was slightly increased (from 65.8% to 69.7%) using single Al3+ ions as the activator and surprisingly, the activating effect was sharply improved (from 69.7% to 80.6%) after adding EDTA. The activating mechanism of Al3+ ions and EDTA was revealed by adsorption capacity measurements, zeta potential measurements, FT-IR spectroscopy analysis and XPS analysis. Al3+ ions were adsorbed on the rutile surface in the form of Al(OH)(n)(3-n) (n = 0, 1, 2), which increased the zeta potential and the activating sites for anionic collector adsorption. The addition of EDTA removed the surplus Al3+ ions, and prevented the generation of hydrophilic colloidal Al(OH)(3) over the pH range of optimum flotation. |
语种 | 英语 |
WOS记录号 | WOS:000423898000040 |
内容类型 | 期刊论文 |
源URL | [http://ir.sinap.ac.cn/handle/331007/29179] ![]() |
专题 | 上海应用物理研究所_中科院上海应用物理研究所2011-2017年 |
作者单位 | 1.Xiao, W 2.Fang, CJ 3.Wang, J 4.Liang, QN 5.Cao, P 6.Wang, XX 7.Zhang, LJ 8.Qiu, GZ 9.Hu, J |
推荐引用方式 GB/T 7714 | Xiao, W,Fang, CJ,Wang, J,et al. The role of EDTA on rutile flotation using Al3+ ions as an activator[J]. RSC ADVANCES,2018,8(9):4872-4880. |
APA | Xiao, W.,Fang, CJ.,Wang, J.,Liang, QN.,Cao, P.,...&Hu, J.(2018).The role of EDTA on rutile flotation using Al3+ ions as an activator.RSC ADVANCES,8(9),4872-4880. |
MLA | Xiao, W,et al."The role of EDTA on rutile flotation using Al3+ ions as an activator".RSC ADVANCES 8.9(2018):4872-4880. |
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