Diamondoid Supramolecular Coordination Frameworks from Discrete Adamantanoid Platinum(II) Cages

doi:10.1021/jacs.8b03856

CORC > 上海应用物理研究所 > 中国科学院上海应用物理研究所 > 中科院上海应用物理研究所2011-2017年

	Diamondoid Supramolecular Coordination Frameworks from Discrete Adamantanoid Platinum(II) Cages
	Cao, LP ; Wang, PP ; Miao, XR ; Dong, YH ; Wang, H ; Duan, HH ; Yu, Y ; Li, XP ; Stang, PJ
刊名	JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
	2018
卷号	140 期号:22 页码:7005-7011
关键词	Metal-organic Frameworks Rational Design Networks Chemistry Hydrogen Crystalline Complexes Polyhedra Cuboctahedron Metallacycles
ISSN号	0002-7863
DOI	10.1021/jacs.8b03856
文献子类	期刊论文
英文摘要	Recently, porous framework materials with various network-type structures have been constructed via several different approaches, such as coordination interactions, reversible covalent bonds, and non-covalent interactions. Here, we have combined the concepts of supramolecular coordination complex (SCC) and metal-organic framework to offer a new strategy to construct a diamondoid supramolecular coordination framework (SCF) from an adamantanoid supramolecular coordination cage as the tetrahedral node and a difunctional Pt(II) ligand as the linear linker via stepwise orientation-induced supramolecular coordination. The adamantanoid supra molecular coordination cage has four uncoordinated pyridyl groups, which serve as the four vertexes of the tetrahedral geometry in the diamondoid framework. As a result, this diamondoid SCF exhibits an adamantanoid-to-adamantanoid substructure with two sets of pores, including the interior cavity of the adamantanoid cage and the extended adamantanoid space between the individual cages in the framework. In addition, the shape-controllable and highly ordered self-assembly of nanometer-sized diamondoid SCF is observed as micrometer-sized regular octahedrons by evaporation under heating in DMSO. This study demonstrates the potential application of supramolecular coordination complexes in the precise construction of highly regulated porous framework materials.
语种	英语
WOS记录号	WOS:000434895200041
内容类型	期刊论文
源URL	[http://ir.sinap.ac.cn/handle/331007/28971]
专题	上海应用物理研究所_中科院上海应用物理研究所2011-2017年
作者单位	1.Cao, LP 2.Wang, PP 3.Miao, XR 4.Dong, YH 5.Wang, H 6.Duan, HH 7.Yu, Y 8.Li, XP 9.Stang, PJ
推荐引用方式 GB/T 7714	Cao, LP,Wang, PP,Miao, XR,et al. Diamondoid Supramolecular Coordination Frameworks from Discrete Adamantanoid Platinum(II) Cages[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,2018,140(22):7005-7011.
APA	Cao, LP.,Wang, PP.,Miao, XR.,Dong, YH.,Wang, H.,...&Stang, PJ.(2018).Diamondoid Supramolecular Coordination Frameworks from Discrete Adamantanoid Platinum(II) Cages.JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,140(22),7005-7011.
MLA	Cao, LP,et al."Diamondoid Supramolecular Coordination Frameworks from Discrete Adamantanoid Platinum(II) Cages".JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 140.22(2018):7005-7011.