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	Acetic Acid Mediated Sulfonylation of Allenylphosphine Oxides: Divergent Synthesis of Bifunctionalized 1,3-Butadienes and Allenes
	Luo, Kai1,2,5; Zhang, Ling1,2; Ma, Jing1,2; Sha, Qiang1,2; Wu, Lei1,2,3,4
刊名	JOURNAL OF ORGANIC CHEMISTRY
	2017-07-07
卷号	82期号:13页码:6978-6985
英文摘要	An acetic acid-mediated sulfonylation of allenylphosphine oxides with sodium sulfinates is disclosed. This new methodology involves tandem (Ar)O-C(sp(3)) bond cleavage and C(sp(2))/C(sp(3))-SO2 formation toward divergent synthesis of sulfonyl- and phosphinyl-bifunctionalized 1,3-butadienes or allenes, depending on the substitution at the terminal carbon atoms of allenylphosphine oxides. The reaction mechanism is explained via an acid-accelerated synergistic process.
语种	英语
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/38991]
专题	化学研究所_其它
作者单位	1.Nanjing Agr Univ, Jiangsu Key Lab Pesticide Sci, Nanjing 210095, Jiangsu, Peoples R China 2.Nanjing Agr Univ, Dept Chem, Coll Sci, Nanjing 210095, Jiangsu, Peoples R China 3.Chinese Acad Sci, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China 4.Chinese Acad Sci, Inst Chem, Beijing 100190, Peoples R China 5.Nanjing Agr Univ, Coll Plant Protect, Nanjing 210095, Jiangsu, Peoples R China
推荐引用方式 GB/T 7714	Luo, Kai,Zhang, Ling,Ma, Jing,et al. Acetic Acid Mediated Sulfonylation of Allenylphosphine Oxides: Divergent Synthesis of Bifunctionalized 1,3-Butadienes and Allenes[J]. JOURNAL OF ORGANIC CHEMISTRY,2017,82(13):6978-6985.
APA	Luo, Kai,Zhang, Ling,Ma, Jing,Sha, Qiang,&Wu, Lei.(2017).Acetic Acid Mediated Sulfonylation of Allenylphosphine Oxides: Divergent Synthesis of Bifunctionalized 1,3-Butadienes and Allenes.JOURNAL OF ORGANIC CHEMISTRY,82(13),6978-6985.
MLA	Luo, Kai,et al."Acetic Acid Mediated Sulfonylation of Allenylphosphine Oxides: Divergent Synthesis of Bifunctionalized 1,3-Butadienes and Allenes".JOURNAL OF ORGANIC CHEMISTRY 82.13(2017):6978-6985.

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