Synthesis of Hierarchical Porous Metals Using Ionic-Liquid-Based Media as Solvent and Template

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	Synthesis of Hierarchical Porous Metals Using Ionic-Liquid-Based Media as Solvent and Template
	Kang, Xinchen 1,2; Sun, Xiaofu 1,2; Ma, Xiaoxue 1; Zhang, Pei 1; Zhang, Zhanrong 1; Meng, Qinglei 1; Han, Buxing 1,2
刊名	ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
	2017-10-02
卷号	59 期号:41 页码:12683-12686
关键词	Heterogeneous Catalysis Hierarchical Porous Metals Ionic Liquids Material Synthesis Ternary System
英文摘要	It was found that nanodomains existed in the ionic liquid (IL)-based ternary system containing IL 1-ethyl-3-methylimidazole tetrafluoroborate (EmimBF4), IL 1-decyl-3-methylimidazole nitrate (DmimNO(3)) and water, and the size distribution of the domains varied continuously with the composition of the solution. A strategy to synthesize hierarchical porous metals using IL-based media as solvent and template is proposed, and the hierarchical porous Ru and Pt metals were prepared by the assembly of metal clusters of about 1.5 nm using this new method. It is demonstrated that the metals have micropores and mesopores, and the size distribution is tuned by controlling the composition of the solution. Porous Ru was used for a series of hydrogenation reactions. It has an outstanding catalytic performance owing to its special morphology and structure.
语种	英语
WOS记录号	WOS:000423699300002
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/38871]
专题	化学研究所_其它
作者单位	1.Chinese Acad Sci, Inst Chem, Key Lab Colloid & Interface & Thermodynam, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China 2.Univ Chinese Acad Sci, Sch Chem & Chem Engn, Beijing 100049, Peoples R China
推荐引用方式 GB/T 7714	Kang, Xinchen,Sun, Xiaofu,Ma, Xiaoxue,et al. Synthesis of Hierarchical Porous Metals Using Ionic-Liquid-Based Media as Solvent and Template[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2017,59(41):12683-12686.
APA	Kang, Xinchen.,Sun, Xiaofu.,Ma, Xiaoxue.,Zhang, Pei.,Zhang, Zhanrong.,...&Han, Buxing.(2017).Synthesis of Hierarchical Porous Metals Using Ionic-Liquid-Based Media as Solvent and Template.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,59(41),12683-12686.
MLA	Kang, Xinchen,et al."Synthesis of Hierarchical Porous Metals Using Ionic-Liquid-Based Media as Solvent and Template".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 59.41(2017):12683-12686.